This paper reviews the use of modulation spectroscopy for the characterization of a wide variety of semiconductor device structures. Some systems that will be discussed include pseudomorphic GaAlAs/InGaAs/GaAs modulation-doped quantum well high electron mobility transistors (including the 300K determination of the twodimensional electron gas density), GaAlAs/GaAs, InP/InGaAs, InGaP/GaAs,InAlAs/InGaAs and InGaAs/GaAs heterojunction bipolar transistors (including the determination of the built-in fields/doping levels in the emitter and collector regions), GaAs/GaA1As quantum well infrared detectors, quantum well lasers, etc. Particular attention will be paid to non-destructive, contactless techniques such as photoreflectance and contactless electroreflectance that can be performed on entire wafers.