2018
DOI: 10.1021/acsomega.8b00588
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Route for Conversion of Furfural to Ethylcyclopentane

Abstract: A method for conversion of furfural, widely available platform chemical from biomass, to ethylcyclopentane, is reported. Ethylcyclopentane is a cyclic alkane with a relatively high octane number (RON 67, bp 103 °C) and could potentially serve as a drop-in biofuel. The synthetic route includes a transformation of furfural to 1-(furan-2-yl)propan-1-ol that is further subjected to Piancatelli rearrangement to give 5-ethyl-4-hydroxycyclopent-2-en-1-one. The subsequent hydrodeoxygenation affords ethylcyclopentane i… Show more

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