Hematite
as a sustainable photoabsorber material offers a band gap close to
2 eV and photoanode characteristics, but usually requires additional
catalysts to enhance surface redox chemistry during steady
state light energy harvesting for water splitting. Here,
for a highly doped hematite film, sufficient intrinsic photocapacitor
behavior is reported for the conversion of light transients into energy. Residual energy is harvested in a symmetric architecture
with two opposing mesoporous hematite films on conductive glass. Transient
light energy harvesting is shown to occur without the need for water
splitting.