Ru-ReOx/TiO2 catalyzed hydrodeoxygenation of sebacic acid as a model compound of levulinic acid self-condensation: exploration of the role of ReOx

Qu, Yaqi; Wu, Han; An, Hualiang; Zhao, Xinqiang; Wang, Yanji

doi:10.1007/s13399-023-04053-8

Biomass Conv. Bioref.

2023

DOI: 10.1007/s13399-023-04053-8

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Ru-ReOx/TiO2 catalyzed hydrodeoxygenation of sebacic acid as a model compound of levulinic acid self-condensation: exploration of the role of ReOx

Yaqi Qu

Han Wu

Hualiang An

et al.

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2024

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Enhanced Isomerization Performance of Unsupported Ni–Nb–O Catalyst for One-Step Hydrogenation of Jatropha Oil to Alkanes

Yin,

Han,

Meng

et al. 2024

Energy Fuels

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Biolipids and oil hydrogenation are prominent alternatives to petroleum-based fuels. Currently, the catalysts used are limited to deoxidation activity, resulting in the reaction products with a high content of n-alkanes and waxes, necessitating secondary treatment to increase iso-alkane content. Herein, an unsupported Ni−Nb−O catalyst with trifunctional capabilities (i.e., hydrodeoxygenation, hydrocracking, and isomerization) was developed for the efficient conversion of methyl stearate and jatropha oil into small molecular alkanes. The metal ratio significantly affects the catalytic performance, in which Ni/Nb = 2:0.6 exhibited the highest isomerization activity. Moreover, 84% of the deoxidized products are C 8 −C 17 hydrocarbons, with 53.4% being isomeric hydrocarbons. The catalyst also demonstrated excellent stability, maintaining 54% selectivity for C 8 −C 17 iso-alkanes in jatropha oil feedstock during 240 h of operation.

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Enhanced Isomerization Performance of Unsupported Ni–Nb–O Catalyst for One-Step Hydrogenation of Jatropha Oil to Alkanes

Yin,

Han,

Meng

et al. 2024

Energy Fuels

View full text Add to dashboard Cite

show abstract

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Ru-ReOx/TiO2 catalyzed hydrodeoxygenation of sebacic acid as a model compound of levulinic acid self-condensation: exploration of the role of ReOx

Cited by 1 publication

References 30 publications

Enhanced Isomerization Performance of Unsupported Ni–Nb–O Catalyst for One-Step Hydrogenation of Jatropha Oil to Alkanes

Enhanced Isomerization Performance of Unsupported Ni–Nb–O Catalyst for One-Step Hydrogenation of Jatropha Oil to Alkanes

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