2016
DOI: 10.1016/j.nanoen.2016.02.036
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Ruddlesden–Popper perovskite sulfides A3B2S7: A new family of ferroelectric photovoltaic materials for the visible spectrum

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Cited by 78 publications
(73 citation statements)
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“…[183] Both the structure and valance state features determine the superior electrochemical properties and versatile applications of Na 0.33 V 2 O 5 in energy storage. Based on the reported results, Na 0.33 V 2 O 5 has been studied as different roles in various energy storage systems, including as LIB cathode, [59,184,185] LIB anode, [186] SIB cathode, [183,187] supercapacitor electrode, [188] aqueous LIB anode [189,190] and aqueous ZIB cathode. [155] He et al [155] studied the electrochemical properties of Na 0.33 V 2 O 5 nanowires as cathode for aqueous ZIBs.…”
Section: A X V 2 O 5 (A = Li Na and K)mentioning
confidence: 99%
“…[183] Both the structure and valance state features determine the superior electrochemical properties and versatile applications of Na 0.33 V 2 O 5 in energy storage. Based on the reported results, Na 0.33 V 2 O 5 has been studied as different roles in various energy storage systems, including as LIB cathode, [59,184,185] LIB anode, [186] SIB cathode, [183,187] supercapacitor electrode, [188] aqueous LIB anode [189,190] and aqueous ZIB cathode. [155] He et al [155] studied the electrochemical properties of Na 0.33 V 2 O 5 nanowires as cathode for aqueous ZIBs.…”
Section: A X V 2 O 5 (A = Li Na and K)mentioning
confidence: 99%
“…Three naturally occurring materials (enargite, stephanite, and bournonite) have recently been suggested as possible candidates from a pool of around 200 materials using criteria based on band gap, optical response, effective masses, and spontaneous polarization [69]. Similar criteria have been applied to polar and non-polar chalcogenide perovskites in the layered RP phase [55,70]; Ca 3 Z 2 S 7 , Ca 3 Hf 2 S 7 , Ca 3 Zr 2 Se 7 , and Ca 3 Hf 2 S 7 have good band gaps for PV systems and are stable in a ferroelectric phase with non-trivial polarization. The role of the Goldschmidt tolerance factor [71] as a design rule for ferroelectric RP materials has been discussed.…”
Section: In Silico Discovery Of Photoferroic Materialsmentioning
confidence: 99%
“…h) HSE‐predicted bandgaps for Ruddlesden–Popper A 3 B 2 S 7 sorted by the perovskite tolerance factor. g,h) Reproduced with permission . Copyright 2016, Elsevier.…”
Section: Nonhalide Perovskitesmentioning
confidence: 99%
“…By replacing Ba with Ca, the ferroelectric polarization was significantly enhanced albeit at the expense of an increased bandgap to 2.2 eV, as shown in Figure g,h. The potential of chalcogenide ferroelectrics is worth further investigations …”
Section: Nonhalide Perovskitesmentioning
confidence: 99%