Ruthenium(II/III) bipyridine complexes incorporating thiol-based imine functions

Synthesis, characterization, EXAFS investigation and antibacterial activities of new ruthenium(III) complexes containing tetradentate Schiff base

“…The average ÔgÕ value is in the range 2.04-2.1 and these values fit very well with the values obtained for other similar ruthenium(III) complexes [47,48]. The EPR spectrum recorded for 4 at liquid nitrogen temperature (77 K) did not show much variation from that observed at room temperature (Fig.…”

Heteroleptic tris-chelates of ruthenium(ii)-bipyridine-arylazoimidazoles: Synthesis, spectral characterisation and electrochemical properties. Single crystal X-ray structure of [(2,2′-bipyridine)-bis-{1-methyl-2-(p-tolylazo)imidazole}ruthenium(ii)] perchlorate

“…))}.The results are comparable with the other examples of ruthenium() with π-acidic ligands e.g., 2,2Ј-bipyridine, 41,42 2-(arylazo)pyridines,10 2-(arylazo)imidazoles 21 and 2-aryl-(2pyridylmethylene)amine. 38 Electrochemical parameterization of the Ru(III)/Ru(II) redox potential of arylazoimidazole complexes of ruthenium(II) Several complexes of 1-alkyl-2-(arylazo)imidazoles of ruthenium() belong to RuCl 2 (RaaiRЈ) 2 , 21,22 [Ru(bpy) 2 -(RaaiRЈ)](ClO 4 ) 2 24 and [Ru(bpy)(RaaiRЈ) 2 ](ClO 4 ) 2 have been characterised by spectroscopic and electrochemical techniques.…”

Synthesis, characterization, and catalytic applications of Ru(III) complexes containing N-[di(alkyl/aryl)carbamothioyl]benzamide derivatives and triphenylphosphine/triphenylarsine

“…The presence of two 'g' values also indicates an axial symmetry for these complexes and, hence, trans positions are assigned for PPh 3 or AsPh 3 groups [15]. The average 'g' value is in the range of 1.53-1.94 and these values fit very well with the values obtained for other ruthenium(III) complexes [16,17]. On the basis of analytical and spectral data, an octahedral structure has been proposed for all the complexes (Scheme 1).…”