Sentinel-1A and Landsat 8 images have been combined in this study to map rice fields in urban Shanghai, southeast China, during the 2015 growing season. Rice grown in paddies in this area is characterized by wide inter-field variability in addition to being fragmented by other land-uses. Improving rice classification accuracy requires the use of multi-source and multi-temporal high resolution data for operational purposes. In this regard, we first exploited the temporal backscatter of rice fields and background land-cover types at the vertical transmitted and vertical received (VV) and vertical transmitted and horizontal received (VH) polarizations of Sentinel-1A. We observed that the temporal backscatter of rice increased sharply at the early stages of growth, as opposed to the relatively uniform temporal backscatter of the other land-cover classes. However, the increase in rice backscatter is more sustained at the VH polarization, and two-class separability measures further indicated the superiority of VH over VV in discriminating rice fields. We have therefore combined the temporal VH images of Sentinel-1A with the normalized difference vegetation index (NDVI) and the modified normalized difference water index (MNDWI) derived from a single-date cloud-free Landsat 8 image. The integration of these optical indices with temporal backscatter eliminated all commission errors in the Rice class and increased overall accuracy by 5.3%, demonstrating the complimentary role of optical indices to microwave data in mapping rice fields in subtropical and urban landscapes such as Shanghai.