Scalable fabrication of quantum-sized CoS1.97 nanoparticles anchoring on biomass carbon aerogel for energy storage application

Zhang, Maozhuang; Jiang, Degang; Liao, Leiping; Cai, Zhenyu; Huang, Wenjun; Liu, Jingquan

doi:10.1016/j.jallcom.2022.165858

Cited by 10 publications

(10 citation statements)

References 50 publications

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“…[17] The overall electrochemical properties of LDHs materials reported in the literature are much lower than their theoretical properties. [18] Therefore, some improvements have been reported, such as compounding with electrically stable materials, [19][20][21] as well as partial phosphating process. Previous work reports provided research ideas for this work, based on the mesoporous microstructure of petal-like materials, the prepared materials were modified to improve their electrochemical stability.…”

Section: Introductionmentioning

confidence: 99%

Facile Sulfuration Route to Enhance the Supercapacitor Performance of 3D Petal‐like NiV‐Layered Double Hydroxide

et al. 2022

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The charge conductivity properties and ionic delivery of pseudocapacitive materials are important factors for the charge storage process. Herein, the new petal-like S-NiVlayered double hydroxide (LDH) materials are successfully synthesized by a presynthetic solvothermal reaction and a sulfidation modification procedure. The specific capacitance of the new petal-like S-NiV-LDHs electrode reaches 1403 F g À1 when the current density is 1 A g À1 , and this is attributed to Ni 3 S 2 formed on the surface of NiV-LDHs. When the current density is up to 20 A g À1 , the rate performance of the new petal-like S-NiV-LDHs electrode is 65.04%. It can be seen that the comprehensive electrochemical performance of the new petal-like S-NiV-LDHs is better than the petal-like NiV-LDHs before modification. When the power density of the S-NiV-LDHs//activated carbon asymmetric supercapacitor cell is 2278.48 W kg À1 , its energy density is 20 Wh kg À1 . The innovation of this work lies in that, based on the microstructure of petal-like NiV-LDHs with rich mesoporous structure, the surface of petal-like NiV-LDHs is slightly sulfurized, which makes the new petal-like S-NiV-LDHs electrode material have smaller electrochemical impedance, richer oxidation states, richer chemical active sites, better energy storage, and cycle stability.

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Section: Introductionmentioning

confidence: 99%

Facile Sulfuration Route to Enhance the Supercapacitor Performance of 3D Petal‐like NiV‐Layered Double Hydroxide

et al. 2022

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“…Lithium-ion batteries (LIBs) have tremendous prospects to meet the ever-increasing demands in the field of mobile electronics and electric vehicles since they have the advantages of high output voltage, generous specific capacity, energetic density, comparatively lightweight, excellent recyclability, and freedom from memory effects. − However, as a conventional intercalation-type anode material, graphite suffers from low theoretical capacity (372 mA h g –1 ), high lithium plating risk, and insufficient multiplication capacity in commercial LIBs. − To push back these limitations, it is necessary to develop innovative anode materials with high performance …”

Section: Introductionmentioning

confidence: 99%

“…4−6 To push back these limitations, it is necessary to develop innovative anode materials with high performance. 7 Attractively, with the development of two-dimensional (2D) material and nanotechnology, multimorphological and surfacechemically modified two-dimensional materials possess unique physicochemical properties, which endow them with distinctive properties for playing an essential role in energy storage devices. As 2D materials, the large-scale ion-accessible interface of MXene can accelerate ion transport and charge transfer.…”

Section: Introductionmentioning

confidence: 99%

Electrostatics and Chemistry Combination Divalent Cobalt Ions and Alkali-Treated MXene for High-Performance Lithium-Ion Batteries

Xiao

Zhang

et al. 2022

Energy Fuels

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To break through the drawback of the low capacity of graphite as an anode material for lithium-ion batteries (LIBs), the development of novel electrode materials is crucial for highperformance LIBs. Recently, MXene with a two-dimensional nanosheet structure has attracted extensive attention due to its numerously exposed lithium storage sites and shortened transport paths as well as superior conductivity. Here, the Co-doped MXene (Co@MXene) composite-based anode for LIBs was prepared using alkali-treated MXene matrix and Co ions through electrostatic adsorption under relatively mild conditions, delivering excellent reversible capacity (1283.2 mA h g −1 at 0.1 A g −1 after 120 cycles) and long-term stability (349.4 mA h g −1 at 1 A g −1 after 1000 cycles). Impressively, the preparation of anodes in a simple method and under moderate operating conditions is superior to the conventional preparation approach, which facilitates practical applications. This work provides ideas for the design of advanced LIB anode materials with quick reaction kinetics, presenting tremendous potential in electrochemical energy storage applications.

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“…In EES, conventional capacitors and LIBs contain elevated power and excessively high energy density. To fill the gap between batteries and capacitors, supercapacitors (SCs) were developed, which are uniquely characterized by high charge diffusion kinetics, exceptional recyclability, low maintenance, adequate pulsed power, and a long lifespan [3–6] . SCs are used in portable consumer gadgets, hybrid electric vehicles, and medical implants, where large amount of power and energy density are critical.…”

Section: Introductionmentioning

confidence: 99%

“…SCs are used in portable consumer gadgets, hybrid electric vehicles, and medical implants, where large amount of power and energy density are critical. SCs comprise electrical EDLCs and pseudo‐capacitors rely on faradaic charge transfer reactions and fast surface‐redox processes [4–6] . Owing to their insignificant energy density, EDLC‐based SCs have restricted prospective for energy storage uses that are desirable [7,8] .…”

Section: Introductionmentioning

confidence: 99%

Pseudocapacitive Features of Freestanding Nickel‐Zinc Organometallic Nanostructure for High‐energy Density Coin‐cell Asymmetric Supercapacitors

Zeng

Devarayapalli

et al. 2022

Chemistry An Asian Journal

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Binder-free two-dimensional mesh-like structure of nickel-zinc metal-organic framework on in-situ-coated carbon cloth (NiÀ Zn MOF/CC) and NiÀ Zn MOF powder were developed via a solvo-hydrothermal reaction for electrochemical storage application. The electrochemical properties of these electrodes show that the electrodes self-assembled on carbon cloth substrates exhibit remarkably excellent performance. The NiÀ Zn MOF/CC electrode exhibited a capacitance of 653.54 F/g at 1 A/g through a capacity retaining of 87.65% after 10000 cycles. Furthermore, the NiÀ Zn MOF//AC coin-cell asymmetric supercapacitor device (CASD) exhibited remarkable energy and power densities of 54.31 Wh/kg and 825 W/kg, respectively, with adequate capacitance retention up to 94.63% over 5000 cycles at 1.5 V. The CASD also exhibited a significant power density of 4950 W/kg at 19.67 W h/kg, which suggests that these in-situ developed MOF-based electrodes may discover application in energy storage devices.

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Scalable fabrication of quantum-sized CoS1.97 nanoparticles anchoring on biomass carbon aerogel for energy storage application

Cited by 10 publications

References 50 publications

Facile Sulfuration Route to Enhance the Supercapacitor Performance of 3D Petal‐like NiV‐Layered Double Hydroxide

Facile Sulfuration Route to Enhance the Supercapacitor Performance of 3D Petal‐like NiV‐Layered Double Hydroxide

Electrostatics and Chemistry Combination Divalent Cobalt Ions and Alkali-Treated MXene for High-Performance Lithium-Ion Batteries

Pseudocapacitive Features of Freestanding Nickel‐Zinc Organometallic Nanostructure for High‐energy Density Coin‐cell Asymmetric Supercapacitors

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