A heterojunction photodetector was fabricated for the
first time
via chemical vapor deposition by combining a p-type WSe2 monolayered triangular flake with a p-type Si substrate. Under illumination,
the p–p isotype heterojunction exhibited a broad photoresponse
range of 400–1550 nm under LED and laser light. The introduction
of monotriangular and atomic thick p-WSe2 flakes onto p-type
Si greatly increased the photodetection capability with a long carrier
lifetime and robust light absorption. The best performance of this
device exhibited a minimized dark current of 5 nA, a record high photocurrent-to-dark-current
ratio of ∼28111.88, an ultrahigh detectivity of 2.075 ×
1015 jones, a high external quantum efficiency (EQE) of
133132%, and a high responsivity of 568.6 A/W under light illumination
of 532 nm with 9.17 mW/cm2 intensity. These engrossing
results indicate that this p-WSe2/p-Si heterojunction device
has considerable potential for applications in next-generation photodetectors.