In this research,
a new diffusion mechanism called “double
cross-phase diffusion” is introduced and applied to simulate
the non-equilibrium gas injection process into fractured rocks. This
new mechanism represents additional multicomponent gas diffusion into
the crude oil through the water phase, existing in porous media as
initial water saturation. Therefore, a lab-scale simulator, by implementing
the generalized Fick’s law of multicomponent diffusion, is
developed and used for predicting the experimental data of oil recovery
during CO
2
injection in chalk fractured rocks in the presence
of initial water saturation. The results revealed a significant difference
in the oil recovery predicted by the model when the double cross-phase
diffusion mechanism is considered. The transient behavior of produced
oil composition, predicted by the simulation model, is matched well
with the experimental data. The portion of active oil recovery mechanisms
in the system has been evaluated for the first time and it was observed
that the molecular diffusion mechanism induced 75.4% of the total
oil transfer rate in the initial time oil recovery, in which 23.1%
of this value was supplied by the double cross-phase diffusion mechanism,
which is an interesting finding. Results of sensitivity analysis showed
that by increasing the initial water saturation, the impact of the
double cross-phase diffusion mechanism on oil recovery increases.
In contrast, the transferred rate by the diffusion mechanism decreases
from 85.4% to 60.8% when matrix permeability increases from 0.1 to
10 mD. The results of this work illustrate that the double cross-phase
diffusion mechanism introduced in this study plays a significant role
in the simulation results since the water is responsible for accelerating
the diffusivity of CO
2
into the crude oil and, in consequence,
increasing the oil recovery.