“…In the present research, we applied this approach to speleothems via a new procedure in which spectroscopic analyses are combined with a carbon extraction method that consumes only small amounts of material. Although solid-phase fluorescence has become a commonly used technique for analyzing speleothems (Crowell & White, 2012;Orland et al, 2014;Perrette et al, 2005;Webb et al, 2014), results have to be interpreted with caution (McGarry & Baker, 2000). In addition, quantifying the organic carbon content of speleothems requires a large amount of calcite for the solid/liquid extraction phase Hartland et al, 2014;Li et al, 2014;Ramseyer et al, 1997;Van Beynen et al, 2001), which is incompatible with studies of carbon fluxes over short timescales and prevents results being combined with high-resolution Solid Phase Fluorescence (SPF) analyses.…”