Gafchromic films are widely used in radiotherapy using photons, electrons and protons. Dosimetric characteristics of the films in terms of beam-quality is of great importance for a better evaluation of the absorbed-dose in the clinic. In proton-therapy, film's response has been reported in terms of track-average, L Δ,T , or dose-average, L Δ,D , linear energy transfer (LET), concluding that L Δ,D is a more reliable parameter than L Δ,T. Nonetheless, in photon-beams, the film's response is generally scrutinised in terms of photon-energy. This work aimed at investigating, the total (TEF) and secondary (SE) electron fluence produced in EBT3 and MD-V3 films exposed to 20 kV-160 kV x-ray and 60 Co beams and their corresponding L Δ,T and L Δ,D to determine their influence on the film's relative-efficiency, RE Film. Regardless the film-model, at energies below 100 keV, L Δ,D for TEF are about 1.7 to 2.5 times those of L Δ,T while for SE they are relatively similar (8-29%). For 60 Co-gamma, L Δ,D for tef and Se are approximately 9 and 4 times L Δ,T , respectively, which implies that L Δ,D is more important for highphoton energies. Independent of the electron-fluence and film-model, RE Film is almost constant at low average-LET, rapidly increases and thereafter steadily rises with average-LET. The RE Film −LET curve indicated that L Δ,D is more sensitive to small change than L Δ,T and if it is evaluated for SE, it would even be more appropriate to better describing the dosimeter response induced by photons in terms of ionization-density instead of L Δ,T for TEF, as generally done. Based on these results, once can conclude that the effect of the average-LET on the film's response should be considered when use for clinicaldosimetry using photons and not only the energy. After the introduction of the linear energy transfer (LET) concept by Zirkle and colleagues 1 , the international commission on radiation units and measurement (ICRU) 2 has adopted two non-stochastic quantities to describe the quality of an ionising radiation beam: the track-average LET, L Δ,T , which describes the average energy lost by charged particles due to collisions per distance travelled with energy transfers less than some specific Δ value and the dose-average LET, L Δ,D , that corresponds to the average LET associated to the absorbed dose distribution 2. Since then, L Δ,T has been conventionally used to quantify the radiation-induced effect in any biological 3-6 and physical 7-12 systems. During the last few years, the dose-average LET, L Δ,D has received some particular importance due to the extensive use of protons for radiotherapy treatment where there is an interest for including, into the treatment planning system, parameters that are clinically and biologically relevant 13-15. In terms of macroscopic dosimetric parameters, Paganetti and colleagues have reported that L Δ,D is more suitable for studying the biological effectiveness instead of L Δ,T 13,15 while Guan and collaborators suggested the use of both quantities, but at different energy ...