Optimization of plant fertilization is an important element of all quality systems in primary production, such as Integrated Production, GLOBAL G.A.P. (Good Agriculture Practice) or SAI (Sustainable Agriculture Initiative). Fertilization is the most important element of agricultural treatments, affecting the quantity and quality of crops. The aim of the study was to assess greenhouse gas (GHG) emissions in the cultivation of Chinese cabbage, depending on the technological variant. The factor modifying the production technology was the use of fertilizers with a slow release of nutrients. One tonne of marketable Chinese cabbage crop was selected as the functional unit. To achieve the research goal, a strict field experiment was carried out. Calculation of the total amount of GHG emitted from the crop was made in accordance with ISO 14040 and ISO 14044. The system boundaries included the production and use of fertilizers and pesticides, energy consumption for agricultural practices and the emission of gases from soil resources and harvesting residue. The use of slow-release fertilizers resulted in a greater marketable yield of cabbage compared to conventional fertilizers. The results of the research indicate a significant potential for the use of slow-release fertilizers in reducing agricultural emissions. From the environmental and production point of view, the most favourable variant is the one with 108 kg N·ha−1 slow-release fertilizers. At a higher dose of this element, no increase in crop yield was observed. At this nitrogen dose, a 30% reduction in total GHG emissions and a 50% reduction in fertilizer emissions from the use of per product functional unit were observed. The reference object was fertilization in accordance with production practice in the test area.