1992
DOI: 10.1002/anie.199211891
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Selective Oxidation of Methane to CO and H2 over Ni/MgO at Low Temperatures

Abstract: Communications may be submitted in English cw in German. Further details sion of communications can be found tie to Authors" reprdtlced in the JBnuary issue of the journal. Copies t h m f m y be obtained from the editorial office upon request.The energy-efficient conversion of methane (or natural gas) to CO and H, (1.e. to syngas, a versatile feedstock for ammonia, methanol, and Fischer-Tropsch synthesis as well as hydrogenation and carbonylation processes) is of great practical importance in the present energ… Show more

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Cited by 113 publications
(45 citation statements)
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“…In SRM, H 2 /CO ratio is higher than 3, which is not suitable for the Fischer-Tropsch and methanol syntheses. As an alternative, catalytic partial oxidation of methane (POM) to H 2 and CO has advantages such as mild exothermicity, suitable H 2 /CO ratio for the Fischer-Tropsch and methanol syntheses, and very short residence time [3][4][5][6][7]. However, POM has disadvantages such as explosion danger and difficulty in controlling the operation.…”
Section: Introductionmentioning
confidence: 99%
“…In SRM, H 2 /CO ratio is higher than 3, which is not suitable for the Fischer-Tropsch and methanol syntheses. As an alternative, catalytic partial oxidation of methane (POM) to H 2 and CO has advantages such as mild exothermicity, suitable H 2 /CO ratio for the Fischer-Tropsch and methanol syntheses, and very short residence time [3][4][5][6][7]. However, POM has disadvantages such as explosion danger and difficulty in controlling the operation.…”
Section: Introductionmentioning
confidence: 99%
“…One important catalytic reaction is the partial oxidation of natural gas to hydrogen and carbon monoxide (synthesis gas), which can be regarded as the first step to convert natural gas into liquid products such as methanol, DME, or synthetic fuels [12][13][14][15][16][17][18][19][20][21]. Typically, supported noble metals are used for this reaction.…”
Section: Introductionmentioning
confidence: 99%
“…However, all these processes involve the formation of large amount of CO x as by-product. [2][3][4] Hydrogen generated by these conventional methods can be utilized by the low temperature fuel cells only if CO x (CO for PEM and CO 2 for AFC) are completely eliminated (to ppm levels) from the stream prior to its introduction into the fuel cell. The process required to eliminate CO from the hydrogen produced in the steam reformer is briefly described below.…”
Section: Introductionmentioning
confidence: 99%