Self-assembly of a novel 3D copper(I)-tetrazolate supramolecular framework via interpenetration of porous 2D double-layer motifs

The reaction of NiCl2 and 3‐hydrazine‐4‐amino‐1,2,4‐triazole (Hatr) in the mixed solvent of EtOH and H2O yielded a dimer compound ([Ni2(Hatr)2(H2O)2(EtOH)2Cl2]Cl2·EtOH) with water and EtOH molecules coordinated to nickle ions. It crystallized in trigonal space group R‐3, a=b=29.67(1) Å, c=8.95(7) Å, β=120(1)°, as determined by single‐crystal X‐ray diffraction. Then, they were fully characterized by the IR spectroscopy, differential scanning calorimetry (DSC), thermogravimetry (TG), and elemental analysis.

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Chlorine‐Induced Hydrogen‐Bonding Network of A Novel Dimer Based on Nickel and Tridentate Ligand: 3‐Hydrazine‐4‐amino‐1,2,4‐Triazole

Zhao

Liu

et al. 2015

Chin. J. Chem.

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Supramolecular Properties Directed by Weak Interactions in a Copper (II) Complex Based on 8-Hydroxy Quinoline-Pyridine Binary Ligand Systems: Crystal Structure and Hirshfeld Surface Analyses

Bhattacharjee

Adhikari²,

Butcher

2021

J Chem Crystallogr

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Metal-Organic Framework Constructed by Copper(I) Cyanide and Ethyl Isonicotinate Through Hydrogen Bonding

Etaiw

El‐bendary

2010

J Inorg Organomet Polym

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Self-assembly of a novel 3D copper(I)-tetrazolate supramolecular framework via interpenetration of porous 2D double-layer motifs

Cited by 25 publications

References 45 publications

Chlorine‐Induced Hydrogen‐Bonding Network of A Novel Dimer Based on Nickel and Tridentate Ligand: 3‐Hydrazine‐4‐amino‐1,2,4‐Triazole

Chlorine‐Induced Hydrogen‐Bonding Network of A Novel Dimer Based on Nickel and Tridentate Ligand: 3‐Hydrazine‐4‐amino‐1,2,4‐Triazole

Supramolecular Properties Directed by Weak Interactions in a Copper (II) Complex Based on 8-Hydroxy Quinoline-Pyridine Binary Ligand Systems: Crystal Structure and Hirshfeld Surface Analyses

Metal-Organic Framework Constructed by Copper(I) Cyanide and Ethyl Isonicotinate Through Hydrogen Bonding

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