Self-assembly of Ag(I) helicates with new enantiopure 5,6-Chiragen type ligands

Abstract

Two new chiral bis-bidentate, C2-symmetrical ligands belonging to the Chiragen family have been synthesised and characterised. They are designed for polynuclear self-assemblies since the two (À)-5,6-pinenebipyridines units are connected by bridges whose length and rigidity avoids the coordination of the bipyridine moieties to the same metal centre. The ligand L1 with a 1,4-dimethylene naphthalene bridge leads, by complexation with Ag(I) cations, to a polymeric, single stranded helix. The helical pitch contains five metal centers, two consecutive metal centers being connected by a bis-bidentate, helically wrapped ligand, one up and the other down resulting in a coordination number four. The chirality (K) around each metal centre is controlled by the six asymmetric carbons of the ligands and the homochirality of the metal centers gives rise to a P orientation at the helix level. The 1 H-NMR measurements of these species in solution indicate a temperature dependent behaviour pointing out possible equilibria between various [Ag n L n ] n+ fragments as confirmed by MS-spectroscopy. The ligand L2 with a 4,4 0 -dimethylene-1,1 0 -biphenyl bridge reacts with Ag(I) and lead to well resolved and temperature independent 1 H-NMR spectra suggesting the formation of a circular helicate.

Tautomerism and Self-Association in the Solution of New Pinene-Bipyridine and Pinene-Phenanthroline Derivatives

“…Ligands with an annellated pinene backbone have been used extensively for chiral induction in coordination compounds of d and f metal ions, giving rise to well defined, enantiopure supramolecular structures [1][2][3][4][5]. Their ability to control the metal centers' chirality makes them attractive not only in the field of supramolecular chemistry [2], but also for various applications like enantioselective catalysis or single chiral molecular magnets [6][7][8][9].…”