Self‐Assembly of Octaaminoamido Derivatives of Resorcin[4]arene in Water − A “Cell‐Like” Submicron‐Scale Hydrogel Structure

Kazakova, E. Kh.; Morozova, Julia E.; Prosvirkin, A. V.; Pich, Andrij; Gubanov, Eduard P.; Muslinkin, A. A.; Habicher, Wolf D.; Коновалов, А. И.

doi:10.1002/ejoc.200400124

Cited by 18 publications

(9 citation statements)

References 27 publications

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“…Dynamic light scattering study and scanning electron microscope images have demostrated the formation of nanodimensional aggregates and submicron-scale`cell-like' aggregates, respectively. 197 …”

Section: Chemistry Of Calix[4]resorcinarenesmentioning

confidence: 99%

Chemistry of calix[4]resorcinarenes

Jain¹,

Kanaiya

2011

Russ. Chem. Rev.

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The review demonstrates the progress in the The review demonstrates the progress in the chemistry of calix[4]resorcinarenes over the last decade. chemistry of calix[4]resorcinarenes over the last decade. Special attention is paid to their synthesis, conformational Special attention is paid to their synthesis, conformational behaviour, functionalization and ability to serve as cavi-behaviour, functionalization and ability to serve as cavitands and capsules, to form monolayers and host ± guest tands and capsules, to form monolayers and host ± guest complexes. Practical applications of calix[4]resorcinarenes complexes. Practical applications of calix[4]resorcinarenes and their derivatives in various fields are surveyed. The and their derivatives in various fields are surveyed. The bibliography includes 296 references bibliography includes 296 references.

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Section: Chemistry Of Calix[4]resorcinarenesmentioning

confidence: 99%

Chemistry of calix[4]resorcinarenes

Jain¹,

Kanaiya

2011

Russ. Chem. Rev.

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“…Tetradodecyloxyphenylencalix [4]resorcinarene 1 and tetramethyloxyphenylencalix [4]resorcinarene 2 were synthesised according to the procedure described earlier (11,12). MO, AO5 and CR were received from SigmaAldrich (Moscow, Russia).…”

Section: Methodsmentioning

confidence: 99%

Amidoamine calix[4]resorcinarene-based oligomers and polymers as efficient sorbents of azo dyes from water

Shalaeva

Morozova

Mironova

et al. 2015

Supramolecular Chemistry

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2015) Amidoamine calix [4]resorcinarene-based oligomers and polymers as efficient sorbents of azo dyes from water, Supramolecular Chemistry, 27:9, 595-605,The sorption behaviour of three kinds of macrocyclic sorbents -amidoamine tetradodecyloxyphenylencalix [4] resorcinarene 1 and tetramethyloxyphenylencalix[4]-resorcinarene 2; composition of calix[4]resorcinarene 1 1 2, and novel P.1 and P.2 polymers with amidoamine calix[4]resorcinarene units towards three water-soluble azo dyes -methyl orange (MO), acid orange (AO5) and Congo red (CR) was studied. All sorbents form supramolecular complexes with the aforesaid dyes. The best sorbent for MO was shown to be polymer P.1, for the AO5 -composition 1 1 2 and for the CRmacrocycle 2, with high sorption capacities (373, 497 and 625 mg/g, respectively). The main factor in the binding of dyes by all studied sorbents proved to be surface electrostatic interactions. In addition to the Coulomb interactions, the most important factor for the polymers appeared to be the 'net' structure of the polymer with a high concentration of binding sites, providing electrostatic, hydrogen, dipole -dipole and hydrophobic interaction. Hydrophobic substituents in the sorbents exert a significant influence on the dye sorption. The increase of the sorbents' hydrophobicity leads to a lower sorption capacity for MO and CR and a higher sorption capacity for AO5. It was shown that sorption efficiency of the sorbent depends on the 'dye -sorbent' structure conformity.

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“…Using these reactions, a broad range of polyfunctionalized derivatives of resorcinarenes have been synthesized; many of these compounds exhibit acceptor properties towards metal cations. [16][17][18][19][20][21] It is noteworthy that the receptor properties of the synthesized compounds and their selectivity are determined by pre-organization of the macrocyclic core of resorcinarene and the nature of the immobilized ionophoric groups.…”

Section: Introductionmentioning

confidence: 99%

Reactions of resorcinarene with N,N-dimethylcarbamoyl and N,N-dimethylthiocarbamoyl chlorides. Factors affecting the process performance

Maslennikova¹,

Burikhina²,

Serkova³

et al. 2016

Arkivoc

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Carbamoylation and thiocarbamoylation of resorcinarenes in the presence of alkali metal carbonates were studied. The effects of the pre-organization of the resorcinarene molecule, the base used, and the nature of the acylating reagent on the reaction outcome were demonstrated. It was shown that octacarbamoylated resorcinarenes in the boat conformation show high absorption properties and selectivity towards cesium cations.

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Self‐Assembly of Octaaminoamido Derivatives of Resorcin[4]arene in Water − A “Cell‐Like” Submicron‐Scale Hydrogel Structure

Cited by 18 publications

References 27 publications

Chemistry of calix[4]resorcinarenes

Chemistry of calix[4]resorcinarenes

Amidoamine calix[4]resorcinarene-based oligomers and polymers as efficient sorbents of azo dyes from water

Reactions of resorcinarene with N,N-dimethylcarbamoyl and N,N-dimethylthiocarbamoyl chlorides. Factors affecting the process performance

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