Abstract:The design and synthesis of three kinds of arylamide molecules (compounds 1~3) containing halogen bonding donor and acceptor fragments, and the exploration and analyzation of different action modes of halogen bonding in solid phase were reported. Compounds 1 and 2 contain two tetrafluoroiodobenzene fragments, and compound 1 also contains a halogen receptor fragment-pyridine group. Isobutyl groups are introduced into the molecule to increase its solubility and crystallinity. And a pyrimidine fragment was introd… Show more
The role of the C–I⋯O halogen bonding in crown ether chemistry has been analyzed and rationalized by using thirteen newly synthesized cocrystals as models.
The role of the C–I⋯O halogen bonding in crown ether chemistry has been analyzed and rationalized by using thirteen newly synthesized cocrystals as models.
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