This paper reports the formation of GaAs V-grooves with well-controllable notch angles. The key methodology used to control the notch angle of a V-groove is to preset the temperature of the etching chemicals. Due to increased chemical reaction at the GaAs surface at high temperature, diffusion-limited etching dominates the etched process, resulting in highly isotropic etched profiles. It is found that the notch angle of a V-groove increases with increasing temperature of the etching chemicals. The etching angle used to define the slope of a V-groove increases from 30 to 55 • as the temperature decreases from 96 • C to 0 • C. Then V-gates formed by depositing Au metal on V-grooves with different notch angles were employed in the fabrication of InGaP/InGaAs heterojunction doped-channel FETs (HDCFETs). Effects of temperature-dependent notch angle on V-gate HDCFETs were investigated in detail, including dc, ac performances and short-channel effects. Experimental results reveal that a small notch-angle V-gate is quite promising for high-frequency applications. Finally, comparisons between simulated results for planar-gate HDCFETs and experimental results for V-gate HDCFETs are used to determine the equivalent gate length of a V-gate. It is found that the equivalent gate length of a V-gate is in the range of 0.1-0.2 µm.