“…Recently, by taking the advantages of supramolecular chemistry (23,24) in regulating mechanical integrity through reversible cross-linking (25)(26)(27), people have developed silicone-based supramolecular materials with unique features of intrinsic healing, stimuli responsiveness, flexibility, elasticity, and toughness (28). These properties make them promising candidates in the emerging and developed fields, such as artificial skin (29), soft robotics (30), and advanced coating applications (18)(19)(20). However, in accordance with coating applications, current supramolecular silicones lack satisfactory stiffness and mechanical strength, their bonding capacity on various substrates has not been well studied, and the effect of incorporated chemical motifs that provide dynamic bonding on liquid repellency remains unknown.…”