We report a new discovery of Yb3+-doped ultrafast scintillators based on the Yb3+ charge transfer luminescence. Transparent ceramic Yb3+-doped Y2O3, Sc2O3, Lu2O3, and Yb2O3 were prepared by sintering. When irradiated by γ- and X-rays, they showed a well detectable photoabsorption peak in the pulse height spectra and ultrafast scintillation decay dominated by the decay time of about 1 ns. For the first time, the Yb3+-doped oxide materials show detectable scintillation in the pulse height measurement at room temperature with ultrafast scintillation decay.