This is the continuation of Vinogradov, Paris, Yanushkevichiene (2012a) (see [34]). Members of the power-variance family of distributions became popular in stochastic modelling which necessitates a further investigation of their properties. Here, we establish Zolotarev duality of the refined saddlepoint-type approximations for all members of this family thereby providing an interpretation of the Letac-Mora reciprocity of the corresponding NEF's. Several illustrative examples are given. Subtle properties of related special functions are established.