Separation Performance of MOFs Zn(ISN)2·2H2O as Stationary Phase for High-Resolution GC

Zhang, Xinhuan; Xie, Sheng‐Ming; Aihong, Duan; Wang, Bang‐Jin

doi:10.1007/s10337-013-2484-9

Cited by 39 publications

(11 citation statements)

References 29 publications

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“…Linear alkanes were also used to test separation effciency of chiral MOFs GC columns by Xie and Zhang et al. For example, chrial MOFs inclouding [Cu(sala)] n , Co‐( d ‐Cam) 1/2 (bdc) 1/2 (tmdpy), InH( d ‐C 10 H 14 O 4 ), Zn(ISN) 2 ⋅2 H 2 O, Ni( d ‐cam)(H 2 O) 2 , and [(CH 3 ) 2 NH 2 [Cd(bpdc) 1.5 ]⋅2DMA clearly separated linear alkanes (n‐C 10 to n‐C 15 ). The separation mechanism of chiral MOFs for linear alkanes separation was the same as other MOFs, which is mainly relying on van der Waals interaction forces.…”

Section: Application Of Mofs In Gas Chromatographic Separationmentioning

confidence: 99%

Metal–Organic‐Framework‐based Gas Chromatographic Separation

Tang

2019

Chemistry An Asian Journal

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Metal-organic frameworks (MOFs)h ave been applied in various fields because of their fascinating structures and excellent properties. MOFs can serve as stationary phases in gas chromatography (GC), which has led to exceptional improvements of performance. Here, we summarize the application of MOFs in GC based on the classification of analytes. The advantages and separation mechanism of MOFs as stationaryp hases in GC are discussed in combination with the characteristics and structures of MOFs. The limitationsa re also summarized in this review,w hich can provide prospects on furtherr esearch for the applications of MOFs.

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Section: Application Of Mofs In Gas Chromatographic Separationmentioning

confidence: 99%

Metal–Organic‐Framework‐based Gas Chromatographic Separation

Tang

2019

Chemistry An Asian Journal

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“…Moreover, Yuan and coworkers also utilized chiral MOFs as CSPs in GC . All of the four reported works followed the same strategy that suspension of chiral MOFs was coated on open tubular columns (30 m × 530 μm id and 2 m × 75 μm id) by a dynamic coating method.…”

Section: Chiral Mofs As Csps In Chromatography Separationmentioning

confidence: 99%

Applications of homochiral metal‐organic frameworks in enantioselective adsorption and chromatography separation

Chang

Wang

et al. 2014

Electrophoresis

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Chiral separation is of great importance for drug development, pharmacology, and biology. Chiral metal-organic frameworks (MOFs) is a new class of porous solid materials with high surface area, large pore size, high chemical stability, uniformly structured cavities, and the availability of modification. The excellent properties of MOFs have attracted intense interest to explore their performance and mechanism in chiral separation. This review summarizes three synthetic strategies of chiral MOFs and their applications in enantioselective adsorption and chromatographic separation. All the experimental and molecular simulation results demonstrated that high enantioselectivity was strongly correlated with a close match between the size of the pore and chiral molecules.

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“…The unparalleled properties of these highly ordered porous materials such as large surface areas of up to thousands m 2 /g, high porosity, tunable pore size, as well as specific adsorption affinities attract the attention of researchers . Chiral MOFs recently emerged as a new type of chiral selectors that appear promising in chromatographic enantioseparations in both gas and liquid phase . For example, chiral MOFs are attracting increased attention as a stationary phase for gas chromatography with good chiral separation capability .…”

Section: Introductionmentioning

confidence: 99%

Polymer‐based monolithic column with incorporated chiral metal–organic framework for enantioseparation of methyl phenyl sulfoxide using nano‐liquid chromatography

Wang

Lamprou

Švec

et al. 2016

J of Separation Science

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A new approach to the preparation of enantioselective porous polymer monolithic columns with incorporated chiral metal-organic framework for nano-liquid chromatography has been developed. While no enantioseparation was achieved with monolithic poly(4-vinylpyridine-co-ethylene dimethacrylate) column, excellent separations of both enantiomers of (±)-methyl phenyl sulfoxide were achieved with its counterpart prepared after admixing metal-organic framework [Zn (benzene dicarboxylate)(l-lactic acid)(dmf)], which is synthesized from zinc nitrate, l-lactic acid, and benzene dicarboxylic acid in the polymerization mixture. These novel monolithic columns combined selectivity of the chiral framework with the excellent hydrodynamic properties of polymer monoliths, may provide a great impact on future studies in the field of chiral analysis by liquid chromatography.

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Separation Performance of MOFs Zn(ISN)2·2H2O as Stationary Phase for High-Resolution GC

Cited by 39 publications

References 29 publications

Metal–Organic‐Framework‐based Gas Chromatographic Separation

Metal–Organic‐Framework‐based Gas Chromatographic Separation

Applications of homochiral metal‐organic frameworks in enantioselective adsorption and chromatography separation

Polymer‐based monolithic column with incorporated chiral metal–organic framework for enantioseparation of methyl phenyl sulfoxide using nano‐liquid chromatography

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