Sequential Paired Electrosynthesis of a Diaryl Ether Derivative Using an Electrochemical Microreactor

Kashiwagi, Tsuneo; Saito, Tsuyoshi; Nishiyama, Shigeru; Atobe, Mahito

doi:10.1246/cl.140046

Cited by 26 publications

(21 citation statements)

References 17 publications

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“…Additional electrochemical oxidation manifolds that have been explored include epoxidation as well as oxidation of thioethers and sulfides, features that were exploited in the synthesis of indinavir, generation of ortho ‐quinone methides and preparation of macrocyclic peptides (Scheme ), respectively. Furthermore, sequential anodic and cathodic manifolds were employed as key steps in Nishiyama's synthesis of O ‐methylthalibrine …”

Section: Anodic Oxidationmentioning

confidence: 99%

Organic Electrosynthesis: Applications in Complex Molecule Synthesis

2019

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Organic electrosynthesis is an enabling and sustainable technology, which constitutes a rapidly expanding field of research. Electrochemical approaches serve as convenient and green alternatives to stoichiometric and toxic chemical redox agents. Electrosynthesis constitutes a promising platform for harnessing the unique reactivity profiles of radical intermediates, expediting the development of new reaction manifolds. This Review highlights both anodic and cathodic methods for the construction of various kinds of complex molecules.

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Section: Anodic Oxidationmentioning

confidence: 99%

Organic Electrosynthesis: Applications in Complex Molecule Synthesis

2019

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“…In the case of homogeneous reactions between two shortlived intermediates, microflow systems [4,133,134] and interdigitated band electrode arrays (IBEA) with narrow interelectrode gaps (i.e., 0.25 -1 mm) that allow an overlap of the cathodic and anodic diffusion layers have been used [2,127,135]. These offer low ohmic losses, enhanced mass transfer, and much higher efficiencies than, for example, parallel plate electrode configurations [127].…”

Section: 6mentioning

confidence: 99%

Paired Electrochemical Processes: Overview, Systematization, Selection Criteria, Design Strategies, and Projection

2017

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In most commercial electrochemical processes, only one of the two sides of the cell produces a desirable reaction, whereas the complementary reaction at the other side simply avoids interference with the target process and/or offers fast kinetics as not to limit it. An overview of several possible paired reaction schemes and their advantages is given, accompanied with specific thermodynamic and kinetic selection criteria, cell and reaction design strategies, and examples from the organic, inorganic, and environmental areas. The unnecessary nomenclature dispersion in this field (e.g., combined, concurrent, conjugate, convergent, coupled, divergent, dual, duet, linear, paired, parallel, simultaneous and synchronous electrochemical processes) is revised and a simple, consistent classification, as well as a homogeneous schematization system, is proposed.

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Section: 6mentioning

confidence: 99%

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Soc.¹

2017

J. Mex. Chem. Soc.

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The Sociedad Química de México was founded in 1956 as a non-profit association to promote the development of the professionals and students of chemistry in education, research, services and industry, and for the diffusion of chemical knowledge. The Sociedad Química de México organizes annually the Mexican Congress of Chemistry and the National Congress of Chemical Education, both congresses include activities of current interest for professionals and students of the chemical sciences. It grants annually the "Andrés Manuel del Río" National Award of Chemistry in the Academic area (field of research and field of education) and in the Technological area (field of technological development). It also grants each year the Rafael Illescas Frisbie Best Bachelor, Master and Doctoral Thesis in Chemical Sciences Awards and the biennial Award of the Sociedad Química de México in honor of the Doctor Mario J. Molina, directed to the professionals in Chemistry Sciences.

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Sequential Paired Electrosynthesis of a Diaryl Ether Derivative Using an Electrochemical Microreactor

Cited by 26 publications

References 17 publications

Organic Electrosynthesis: Applications in Complex Molecule Synthesis

Organic Electrosynthesis: Applications in Complex Molecule Synthesis

Paired Electrochemical Processes: Overview, Systematization, Selection Criteria, Design Strategies, and Projection

Full Issue

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