Substantial coal measure gas is reserved in the Upper
Permian shale
in western Guizhou, China, but the mechanism of gas generation and
enrichment remains unclear. In this study, rock-eval pyrolysis, stable
carbon isotope, and low-temperature N2/CO2 adsorption
(LN2/CO2A) experiments were conducted on coal
measure shale collected from western Guizhou. The geochemical composition
and pore morphology were clarified, and the shale gas generation and
storage characteristics were ultimately revealed. The results show
that the total organic carbon (TOC) contents of most samples exceed
2%, indicating a high organic matter (OM) abundance. The average R
o and T
max are 2.89%
and 576 °C, respectively, corresponding to the overmature stage,
leading to the poor current hydrocarbon generation potential. Unlike
marine shale with dense organic pores, these pores are generally poorly
developed and heterogeneous in the samples. Densely distributed microfractures
are favorable methane migration channels. The pores are dominated
by mesopores, with an average pore volume (PV) proportion of 53.55%,
while the specific surface area (SSA) is mainly contributed by micropores.
The LCO2A-SSA and LCO2A-PV show a positive correlation
with the TOC, T
max, and S1,
but the LN2A-SSA and LN2A-PV are poorly correlated
with these parameters, indicating that micropores are mainly derived
from organic pores and that hydrocarbons generated by OM pyrolysis
are mainly reserved in micropores. When δ13COM shows a negative anomaly, R
o, T
max, and S1 all show a
negative drift in the vertical sequence, suggesting that the chemical
parameters are closely related during thermal maturation. Accompanied
by hydrocarbon generation, 12CH4 is preferentially
separated from the OM, resulting in a higher δ13COM. Meanwhile, the generated methane is mainly reserved in
the form of adsorption, and the micropores/mesopores provide a favorable
place for shale gas storage.