2010
DOI: 10.1007/s11242-010-9665-x
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Shale-Gas Permeability and Diffusivity Inferred by Improved Formulation of Relevant Retention and Transport Mechanisms

Abstract: A theoretically improved model incorporating the relevant mechanisms of gas retention and transport in gas-bearing shale formations is presented for determination of intrinsic gas permeability and diffusivity. This is accomplished by considering the various flow regimes according to a unified Hagen-Poiseuille-type equation, fully compressible treatment of gas and shale properties, and numerical solution of the non-linear pressure equation. The present model can accommodate a wide range of fundamental flow mech… Show more

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Cited by 414 publications
(222 citation statements)
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“…This empirical model is analogous to the one used in coalbed methane and based on the assumption that there is an instantaneous equilibrium between the sorbed gas and the free gas . The Langmuir's isotherm model has been used in much of the literature on shale gas (Cui et al 2009;Civan et al 2011;Ding et al 2014;Guo et al 2014Pan and Connel 2015) and it is given by (1) which can be expressed as (2) where q is the mass of gas adsorbed per solid volume (kg/m 3 ), q a is the standard volume of adsorbed gas per solid mass (m 3 /kg), s is the shale density (kg/m 3 ), M g is the gas molecular weight (kg/mol), V std is the gas molar volume at standard condition (273.15K, 1 atm), V L is the Langmuir gas volume (m 3 /kg), p is the gas pressure (Pa), and p L is the Langmuir gas pressure (Pa). The Langmuir's volume is a function of the organic richness and thermal maturity of shale formation ).…”
Section: Shale Gas Modeling Equationsmentioning
confidence: 99%
“…This empirical model is analogous to the one used in coalbed methane and based on the assumption that there is an instantaneous equilibrium between the sorbed gas and the free gas . The Langmuir's isotherm model has been used in much of the literature on shale gas (Cui et al 2009;Civan et al 2011;Ding et al 2014;Guo et al 2014Pan and Connel 2015) and it is given by (1) which can be expressed as (2) where q is the mass of gas adsorbed per solid volume (kg/m 3 ), q a is the standard volume of adsorbed gas per solid mass (m 3 /kg), s is the shale density (kg/m 3 ), M g is the gas molecular weight (kg/mol), V std is the gas molar volume at standard condition (273.15K, 1 atm), V L is the Langmuir gas volume (m 3 /kg), p is the gas pressure (Pa), and p L is the Langmuir gas pressure (Pa). The Langmuir's volume is a function of the organic richness and thermal maturity of shale formation ).…”
Section: Shale Gas Modeling Equationsmentioning
confidence: 99%
“…Due to these inherent characteristics of gas shale such as, (1) widely dispersed organic matter and (2) nano-scale pore system ), shale gas transport mechanisms do not fully follow Darcy's law. We cannot simply use Darcy's law to calculate matrix permeability of gas shale because of these special phenomena and problems (Civan 2010;Civan et al 2011).…”
Section: Micro Flow Mechanismsmentioning
confidence: 99%
“…Shale gas adsorbed on the surfaces of nanopores follows the mono-layer Langmuir isotherm adsorption equation (Civan et al 2011):…”
Section: Adsorption and Desorptionmentioning
confidence: 99%
“…Based on the model of micro-nano pipes, Beskok and Karniadakis put forward a volumetric flow rate formula with different flow regimes (Beskok and Karniadakis 1999). The Beskok model that describes gas flow in a single tube has been applied to research into tight gas and shale gas flow by Civan et al in which the Knudsen number is used to describe the transport mechanism that incorporates viscous flow and Knudsen diffusion (Civan 2010;Civan et al 2010Civan et al , 2011. Javadpour (2009) considered that Darcy's law and Fick's law can describe gas transport mechanisms in micropores, and Knudsen diffusion is the main gas transport mechanism in nanopores.…”
Section: Introductionmentioning
confidence: 99%