2009
DOI: 10.1021/jp905891q
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Shock Tube and Theory Investigation of Cyclohexane and 1-Hexene Decomposition

Abstract: The decomposition of cyclohexane (c-C(6)H(12)) was studied in a shock tube using the laser-schlieren technique over the temperature range 1300-2000 K and for 25-200 Torr in mixtures of 2%, 4%, 10%, and 20% cyclohexane in Kr. Vibrational relaxation of the cyclohexane was also examined in 10 experiments covering 1100-1600 K for pressures below 20 Torr, and relaxation was found to be too fast to allow resolution of incubation times. The dissociation of 1-hexene (1- C(6)H(12)), apparently the sole initial product … Show more

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Cited by 95 publications
(121 citation statements)
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“…Some decomposition channels were proposed for the initial reactions of cyclohexane (cC 6 H 12 ), which have been reviewed in detail by Kiefer et al [5]. In their work, both the shock tube experimental and theoretical results confirmed that cyclohexane predominantly isomerizes into 1-hexene (C 6 H 12 ) (R1).…”
Section: Reactions Of Cyclohexanementioning
confidence: 96%
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“…Some decomposition channels were proposed for the initial reactions of cyclohexane (cC 6 H 12 ), which have been reviewed in detail by Kiefer et al [5]. In their work, both the shock tube experimental and theoretical results confirmed that cyclohexane predominantly isomerizes into 1-hexene (C 6 H 12 ) (R1).…”
Section: Reactions Of Cyclohexanementioning
confidence: 96%
“…In Kiefer et al's work [5], the rate constants of R1 were measured in experiments and calculated by RRKM theory at various pressures (33,67,133,200 and 266 mbar) in the temperature range of 1300-2000 K. They suggested that the uncertainty of rate constants is within ±30% throughout the range of pressure and temperature. In this work, their calculated rate constant at 33 mbar is used and divided by a factor of 1.5 in the simulation to get a better agreement with the experimental measurement.…”
Section: Reactions Of Cyclohexanementioning
confidence: 99%
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