The distribution of phytoplankton pigment characteristics (С<sub>chl <i>a+b+c</i></sub>/C<sub>chl<i> a</i>, </sub>
C<sub>chl<i> b</i></sub>/C<sub>chl<i> a</i></sub>, C<sub>chl<i> c</i></sub>/C<sub>chl <i>a</i></sub>, C<sub>chl <i>a</i></sub>/C<sub>chl <i>b</i></sub>, C<sub>chl <i>a</i></sub>/C<sub>chl <i>c</i>, </sub> C<sub>pheo <i>a</i></sub>, C<sub>chl <i>a</i></sub>/C<sub>pheo <i>a</i></sub>, C<sub>car</sub>/C<sub>chl <i>a</i></sub>,
and E<sub>480</sub>/E<sub>664</sub> and E<sub>430</sub>/E<sub>664</sub>) in 19 lakes located within the territory of Kyiv is discussed in the paper. The studied lakes differ in their origin, hydrological conditions, and also in the level of anthropogenic load. It has been found that changes in relationship between various groups of pigments correlate with changes in phytoplankton structure. The given pigment indices can be used in assessing the structure of algal communities, the physiological state of algae, their quantitative development, and the ecological state of water bodies.