“…Synthetic preparation of nanoparticles (NPs) confined in organized assemblies or microdomains such as microparticles, microdroplets, micellar microreactors, and emulsions has been intensely researched , owing to the enhanced chemical properties of the NPs confined in such self-assembled systems, which result in a wide variety of functions. − Among NPs, silver NPs (AgNPs) are widely utilized in many fields such as catalysis, − spectroscopy, , sensors, , medical agents, and cancer treatments. , In the one-pot chemical synthesis of AgNPs, the control of the NP size and shape is particularly challenging. ,− Despite the popular use of citrate for the reduction of Ag ions, ,− the interaction between the Ag surface and the citrate ion results in a very slow crystal growth (with size control) compared with other chemical methods (e.g., sodium borate) or those assisted by physical radiation. − To overcome this problem, some approaches such as the stepwise increase in the concentration or the use of additives were reported. In addition, the control of the size of AgNPs is relatively difficult compared with the synthesis of gold NPs (AuNPs) using the citrate reduction method .…”