Simultaneous determination of seven phthalates and four parabens in cosmetic products using HPLC‐DAD and GC‐MS methods

Shen, Hao-Yu; Jiang, Hua; Mao, Hong-Lei; Pan, Gang; Zhang, Lu; Cao, Yun‐Feng

doi:10.1002/jssc.200890039

Cited by 27 publications

(23 citation statements)

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“…This is in the agreement with recent findings [21][22] . In general, higher concentrations of detected phthalates were found in samples isolated using reflux extraction, which is in the agreement with the work of Shen et al 23 . The best representative of this fact is the sample of nail varnish, where using the same solvent reflux extraction yielded 3-10 times higher levels of same phthalate.…”

Section: Resultssupporting

confidence: 86%

Influence of Solvent and Extraction Type on Phthalate Determination in Cosmetic Products

Zeljković¹,

Becirovic²,

Goga³

et al. 2014

Analytical Chemistry Letters

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Phthalate esters are widely used as additives in the manufacturing of different types of plastics in order to increase their flexibility. Extensive use of these chemicals resulted in their presence in various environmental matrices. In the last decade, interest in the phthalate analysis is strongly increased due to their harmful effects on the humans. The aim of this work was investigate of the presence and content of phthalates in several cosmetics products in dependence of solvent and type of extraction used. The content of phthalates was determined by GC-MS using calibration curve method. Among six different extraction types and three solvents, it was found that reflux and ultrasonic extractions gave the highest yields of desired molecules. Used method was fast, reliable for different types of samples, and does not require time-consuming purification of analytes nor special chromatographic columns.

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Section: Resultssupporting

confidence: 86%

Influence of Solvent and Extraction Type on Phthalate Determination in Cosmetic Products

Zeljković¹,

Becirovic²,

Goga³

et al. 2014

Analytical Chemistry Letters

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“…So far, in order to better determine the level of pollution in the environment, several analytical methods for the determination of DBP are developed, such as GC-MS, GC-electron capture detector (GC-ECD), liquid chromatography-electrospray ionization mass spectrometry (LC-ESI-MS), LC-tandem mass spectrometry (LC-MS-MS), high performance liquid chromatography (HPLC), HPLC-diode array detection (HPLC-DAD), HPLCelectrospray-mass spectrometry (HPLC-ES-MS), ultra performance liquid chromatography (UPLC), UPLC-tandem mass s p e c t r o m e t r y ( U P L C -M S-M S ) , u l t r a -f a s t l i q u i d chromatography-mass spectrometry (UFLC-MS), etc. (Chee et al 1996;Lin et al 2003;Sørensen 2006;Shen et al 2007;Feás et al 2008;Wu et al 2008;Thomas et al 2013). Although the above instrument analysis methods are accurate, the instruments are much more time-consuming, expensive and require more skill to operate.…”

Section: Introductionmentioning

confidence: 93%

Biotin-Streptavidin Enzyme-linked Immunosorbent Assay for the Determination of Dibutyl Phthalate in Beverages and Drinking Water Using a Specific Polyclonal Antibody

Sun

Zhuang

2015

Food Anal. Methods

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A specific polyclonal antibody targeting dibutyl phthalate (DBP) was obtained, and a sensitive indirect competitive biotin-streptavidin enzyme-linked immunosorbent assay (BA-ELISA) was developed for the determination of DBP in beverages and drinking water. Under optimal conditions, good linearity was achieved within a range of 0.02 to 8.97 μg·L −1 . The limit of detection (IC 10 ) was 5 ng·L −1 , and the median inhibitory concentration (IC 50 ) was 0.36 μg·L −1 . The BA-ELISAwas highly selective, with lower cross-reactivity values with DBP analogues (lower than 4 %). Finally, the concentrations of DBP in beverages and drinking water by this method ranged from 0.45 to 7.06 μg·L −1 . Satisfactory recoveries (89.5 to 109.5 %) and variation coefficient values (6.0 to 8.7 %) were obtained. The consistency between the results obtained from BA-ELISA and gas chromatography-mass spectrometry (GC-MS) was 98.8 %, which further confirmed that this proposed BA-ELISA immunoassay was reliable, rapid, sensitive, and accurate for monitoring DBP in the environmental samples.

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“…They are also used as solubilizing or stabilizing agents in other applications such as building products (flooring, furniture, and electric cables) (Butte & Heizow, 2002), personal care and cosmetic products (deodorants, hair products and perfumes) (Cao, 2010;Shen et al, 2007), textile industry and pesticide formulation (Koch, Rossbach, Drexler, & Angerer, 2003). However, they are not chemically bonded to polymers, and can easily migrate into foods (Moskovkin, 2002).…”

Section: Introductionmentioning

confidence: 98%

Determination of phthalates in food packing materials by electrokinetic chromatography with polymeric pseudostationary phase

Xing

Cao

et al. 2016

Food Chemistry

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Simultaneous determination of seven phthalates and four parabens in cosmetic products using HPLC‐DAD and GC‐MS methods

Cited by 27 publications

References 0 publications

Influence of Solvent and Extraction Type on Phthalate Determination in Cosmetic Products

Influence of Solvent and Extraction Type on Phthalate Determination in Cosmetic Products

Biotin-Streptavidin Enzyme-linked Immunosorbent Assay for the Determination of Dibutyl Phthalate in Beverages and Drinking Water Using a Specific Polyclonal Antibody

Determination of phthalates in food packing materials by electrokinetic chromatography with polymeric pseudostationary phase

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