PM,, (particles < 10 y m in aerodynamic diameter) and PM,,, (particles < 2.5 y m in aerodynamic diameter) mass, elements, water-soluble nitrate, sulfate, ammonium, sodium, potassium, and organic and elemental carbon were determined in 24-h aerosol samples collected during this period. Federal and state standards for PM,, were exceeded a t both urban and nonurhan sites. PM,, concentrations were generally highest during winter and were dominated by PM,, during this time. The coarse (PM1, minus PM,.,) aerosol fraction constituted more than half of PM,, mass during the summer and fall.PM,, concentrations of secondary ammonium nitrate were elevated during the winter a t all sites. Conversely, concentrations of coarse particle iron, indicative of geologically related dust, were higher under less humid conditions during the summer and fall. Regionwide meteorological and chemical transformation processes influence the secondary (nitrate and sulfate) components of PM,,. Elevated concentrations of coarse-particle dust, however, appear to originate from local emissions, such as agricultural and transportation-related activities, as well as region-wide emissions.