Turbulent superstructures in horizontally extended three-dimensional Rayleigh–Bénard convection flows are investigated in controlled laboratory experiments in water at Prandtl number
${Pr}=7$
. A Rayleigh–Bénard cell with square cross-section, aspect ratio
$\varGamma =l/h=25$
, side length
$l$
and height
$h$
is used. Three different Rayleigh numbers in the range
$10^{5} < {Ra} < 10^{6}$
are considered. The cell is accessible optically, such that thermochromic liquid crystals can be seeded as tracer particles to monitor simultaneously temperature and velocity fields in a large section of the horizontal mid-plane for long time periods of up to 6 h, corresponding to approximately
$10^{4}$
convective free-fall time units. The joint application of stereoscopic particle image velocimetry and thermometry opens the possibility to assess the local convective heat flux fields in the bulk of the convection cell and thus to analyse the characteristic large-scale transport patterns in the flow. A direct comparison with existing direct numerical simulation data in the same parameter range of
$Pr$
,
${Ra}$
and
$\varGamma$
reveals the same superstructure patterns and global turbulent heat transfer scaling
${Nu}({Ra})$
. Slight quantitative differences can be traced back to violations of the isothermal boundary condition at the extended water-cooled glass plate at the top. The characteristic scales of the patterns fall into the same size range, but are systematically larger. It is confirmed experimentally that the superstructure patterns are an important backbone of the heat transfer. The present experiments enable, furthermore, the study of the gradual evolution of the large-scale patterns in time, which is challenging in simulations of large-aspect-ratio turbulent convection.