2019
DOI: 10.7567/1347-4065/ab0c74
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Single crystal growth of nitride and oxynitride phosphors using a gas–solid phase hybrid synthesis method

Abstract: The Al doped Sr2Si5N8:Eu2+ single crystal Sr2AlxSi5−xOxN8−x:Eu2+ (x ≈ 0.7) were grown by our original single crystal growth method and the precise crystal structure was investigated by single crystal X-ray diffraction analysis for the first time. O atoms are partially substituted for only N1 and N5 sites which are connected with the Si/Al atoms to compensate the “Pauling’s second rule”, which indicates the introduction of Al atoms for Si sites restricts the N sites that can be substituted by O atoms. The Sr2Al… Show more

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