Single-site metal–organic framework catalysts for the oxidative coupling of arenes via C–H/C–H activation

Abstract

Heterogeneous palladium single-site MOF catalysts for the oxidative coupling of arenes via C–H/C–H: superior TONs due to active site isolation.

Expanding the Variety of Zirconium‐based Inorganic Building Units for Metal–Organic Frameworks

“…One of the main interests of stable, large pore MOFs is that they are flexible platforms for the immobilization of precious homogeneous metal catalysts . This is especially relevant in the rich domain of C−H activation catalysis, with formation of for example, C−C, C−N, or C−B bonds . Arylboronic acids are very important intermediates in organic synthesis that can be used in a plethora of synthetic procedures .…”

“…Theq uality of the extracted reflection intensities can be increased by coupling ADT with precession electron diffraction (PED). [36][37][38][39][40] Arylboronic acids are very important intermediates in organic synthesis that can be used in ap lethora of synthetic procedures. [34,35] This is especially relevant in the rich domain of C À Ha ctivation catalysis,w ith formation of for example,C ÀC, CÀN, or CÀBb onds.…”

Modulator-Mediated Functionalization of MOF-808 as a Platform Tool to Create High-Performance Mixed-Matrix Membranes

“…catalysis and gas detection. [23][24][25][26] Compared to UiO-66, MOF-808 exhibits a higher surface area and larger pore volume, but at the same time, equally excellent thermal, chemical and mechanical stability. 27 Both UiO-66 and MOF-808 are based on the same Zr6O4(OH)4 clusters, respectively linked by ditopic BDC 2and tritopic 1,3,5benzenetricarboxylate (BTC 3-) linkers.…”

Expanding the Variety of Zirconium‐based Inorganic Building Units for Metal–Organic Frameworks

“…[34,35] This is especially relevant in the rich domain of C À Ha ctivation catalysis,w ith formation of for example,C ÀC, CÀN, or CÀBb onds. [36][37][38][39][40] Arylboronic acids are very important intermediates in organic synthesis that can be used in ap lethora of synthetic procedures. [41][42][43][44][45] Among the different routes to synthesize arylboronic acids,d irect C À Hb orylation of arenes using bis(pinacolato)diboron (B 2 pin 2 )i st he most environmentally benign process,w hich can be efficiently catalysed by homogeneous iridium complexes.…”