A laboratory ultrasound technique has been developed to measure the longitudinal velocity of sound in high purity and density boron carbide and lanthanum hexaboride materials prepared by shock wave compression. Using the measured value of the longitudinal velocity of sound υ L , we have calculated the Young's modulus E, the Bulk modulus K, the Shear modulus G and the Poisson's ratio ν. X-rays diffraction has also been carried out on these materials.