An optical surface Bloch mode [1][2][3][4][5][6][7] is an optical state evanescently bound at a surface on a periodic structure, and the mode frequency is located within a photonic bandgap (PBG). Tamm [8] studied electronic surface Bloch modes. Yeh, Yariv and Hong [1] pioneered the study of optical surface Bloch modes in one-dimensional (1D) periodic dielectric media. The optical surface Bloch mode is an intriguing subject in optical physics and condensed matter physics and is potentially useful for nanophotonic applications such as optical sensing and cavity quantum electromagnetic dynamics (QED) experiments, as the mode is localized at the surface of a photonic crystal within subwavelength scales.A finite-size photonic crystal has multiple crystal terminations (representatively surface planes) unless it has cyclically periodic conditions-Born-von Karman boundary conditions. Figure 1 shows a finite-size woodpile three-dimensional (3D) photonic crystal terminated on both (100) and (001) surface planes. Upper and right panels in Fig. 1 show a (100) surface plane mode on an infinite (100) surface and a (001) surface plane mode on an infinite (001) surface, respectively. The <100>, <010>, and <001> crystal directions are parallel to the x, y, and z axes. For 3D photonic crystals, an intersection of two (three) nonparallel surface planes forms an edge (a vertex). Optical localization at surface intersections is important as it provides new opportunities of low-loss light localization in subwavelength scales without the use of metal. In our work, we consider woodpile dielectric photonic crystals, as they are representative 3D photonic crystals with a complete bandgap and can be fabricated by two-directional etching method [9,10] and by layer-by-layer method [5,11]. Here we report novel localized modes at an edge on a woodpile 3D photonic crystal embedded in vacuum.