The paper presents the new concept of low frictional hybrid composite coatings on nodular cast iron. The structure of it is multilayer and consists of MoS2 and/or WS2 nanoinclusions embedded in the iron nitrides’ zone and relatively deep hard diffusion zone. It offers a low friction coefficient as well as high wear resistance of coated parts. The details of technology as well as the mechanism of layer’s growth have been presented and discussed. The presented technology may be an interesting alternative for chromium-based galvanic coatings of piston rings made of nodular iron using Cr6+.