A new cement-based sealing material, which used Portland
cement
(PC) as a raw material and supplemented several gel components, such
as accelerant, alkali activator, suspension agent, expansion agent,
reinforcing agent, was prepared in this work. The effects of these
components on the fluidity, setting time, and expansion rate of these
sealing materials were investigated by an orthogonal test. The results
show that the water–cement ratio and the reinforcing agent
content, the accelerant content and the water–cement ratio,
and the expansion agent content and the accelerant content are the
most important influencing factors on fluidity, setting time, and
expansion rate, respectively. In addition, the regression models and
response surfaces of the factors were established using a multiple
linear regression method. By this means, the influences of the two
main factors on each performance of this sealing material were accurately
and intuitively reflected for obtaining the optimal value in the optimization
area. The results indicate that the sealing materials possess the
best performances when the water–cement ratio is 1.1, the accelerant
content is 50%, the expansion agent content is 0.1%, and the reinforcing
agent content is 3%, which is corresponding to a fluidity of 360–380
mm, an initial (final) setting time of 60 (80)–80 (100) min,
and an expansion rate of 2–12%. Furthermore, the microstructures
of the optimized sealing material also reveal that the main hydration
products of PC are transformed from layered Ca(OH)
2
crystals
into fine needle-like AFt crystals and C–S–H gels by
the promotion effect of the optimizing ratio, thus leading to a more
compact structure of optimized cement-based sealing materials.