Sodium N‐(t‐butoxycarbonyl)‐N‐diethylphosphoramide

Ho, Tse‐Lok; Fieser, Mary; Fieser, Louis

doi:10.1002/9780471264194.fos09103

Fieser and Fieser's Reagents for Organic Synthesis 2006

DOI: 10.1002/9780471264194.fos09103

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Sodium N‐(t‐butoxycarbonyl)‐N‐diethylphosphoramide

Tse‐Lok Ho¹,

Mary Fieser²,

Louis Fieser³

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2016

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“…The plant Paeonia veitchii has been used in many traditional Asian medicines for hundreds of years . The root of this plant has been shown to have intriguing biological activity, including immunomodulation, anti-inflammation properties, and hypoglycemic action, among others .…”

mentioning

confidence: 99%

A Total Synthesis of Paeoveitol

Liu

et al. 2016

Org. Lett.

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A four-step total synthesis of paeoveitol (1), a recently disclosed norditerpene natural product from Paeonia vetchii, is reported. This highly concise synthetic route was guided by biosynthetic considerations and enabled by an unusual intermolecular ortho-quinone methide [4 + 2]-cycloaddition reaction, which proceeded with excellent regio- and diastereoselectivity. Density functional theory (DFT) calculations point to a crucial intermolecular hydrogen bond and π-π stacking interaction that govern selectivity in this process.

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mentioning

confidence: 99%

A Total Synthesis of Paeoveitol

Liu

et al. 2016

Org. Lett.

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Sodium N‐(t‐butoxycarbonyl)‐N‐diethylphosphoramide

Cited by 1 publication

References 1 publication

A Total Synthesis of Paeoveitol

A Total Synthesis of Paeoveitol

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