. 2004. Phosphorus diffusion from monocalcium phosphate coapplied with salts in a calcareous soil. Can. J. Soil Sci. 84: 447-458. Mixing non-phosphatic salts with fertilizer P influences the solubility and mobility of P in soils. Little evidence, however, is available regarding the mechanisms causing such effects. The objectives of this study were to investigate the effects of mixing fertilizer P with (NH 4 ) 2 SO 4 , MgSO 4 or (NH 2 ) 2 CO on the diffusion of P in a calcareous soil (Gleyed Rego Black Chernozem), and to identify the causes for such effects. To the surface of 50-mm-long soil columns, maintained at field capacity water content, 32 P-labelled monocalcium phosphate (MCP) was applied alone or in combination with (NH 4 ) 2 SO 4 , MgSO 4 or (NH 2 ) 2 CO. Ratios of applied P:N, P:Mg and P:S were 1:5, 1:4.5 and 1:6, respectively. Extraction and analysis of each 2-mm layer of the columns after incubation for 1, 2, 3, and 4 wk revealed that the addition of (NH 4 ) 2 SO 4 and MgSO 4 with MCP significantly increased P diffusion whereas (NH 2 ) 2 CO had little or no effect. The mechanisms of such effects were identified using a multi-ionic, mechanistic, diffusion model. According to model predictions, the dissolution of MCP was increased by more than twofold when mixed with (NH 4 ) 2 SO 4 and MgSO 4 , and by 1.2-fold when mixed with urea. The main difference between SO 4 salts and urea in affecting P diffusion was the competition between the anion of the salt and P for precipitation with Ca. Sulphate competed strongly with P, reducing the precipitation of Ca phosphates. Application of urea increased soil pH initially, but eventually soil pH decreased with nitrification of NH 4 . Initial increase in pH to above 8.0 favoured precipitation of Ca phosphate, but the pH was not high enough to favour CaCO 3 precipitation. The application of P fertilizers with fertilizers containing SO 4 could be beneficial in calcareous soils due to enhancement of P solubility and mobility. Mélanger des sels non phosphatés à un engrais phosphaté (P) modifie la solubilité et la mobilité du P dans le sol. Toutefois, on sait peu de choses sur les mécanismes à l'origine de ce phénomène. L'étude devait préciser comment le fait de mélanger un engrais P avec du (NH 4 ) 2 SO 4 , du MgSO 4 ou du (NH 2 ) 2 CO agit sur la diffusion du P dans un sol calcaire (tchernoziom noir gléyifié Rego) et établir les causes des modifications observées. À cette fin, les auteurs ont appliqué du phosphate monocalcique (PMC) marqué au 32 P avec ou sans (NH 4 ) 2 SO 4 , MgSO 4 ou (NH 2 ) 2 CO au sommet de colonnes de sol de 50 mm de hauteur dont la teneur en eau était maintenue à la capacité maximale du terrain. Les ratios appliqués étaient respectivement de 1:5, 1:4,5 et 1:6 pour P:N, P:Mg et P:S. Après incubation pendant 1, 2, 3 ou 4 semaines, l'extraction et l'analyse de chaque tranche de 2 mm des colonnes révèle que l'addition de (NH 4 ) 2 SO 4 et de MgSO 4 au PMC accroît sensiblement la diffusion du P alors que le (NH 2 ) 2 CO n'a pas d'effet sur ce phénom...