Mechanisms of carbonate deposition in Lake Fryxeli, Taylor Valley, Antarctica (75 0 35'S, 163 0 35'E) have been investigated. The lake lies within an area once covered byRQss Sea 1 ice (c. 20 000 years ago) and its proglaciallake. Lake sediments consist of five units, unit A being the lowermost deposit cored and unit E the uppermost. Three phases of carbonate deposition are evident in these sediments and result from climate changes associated with ice advances andretreat.(1) About 20 000 years ago, a calcareous mud (unit B) was deposited in a deep proglacial Lake Washburn. The carbonate is of biogenic origin, and mixed calcite/ aragonite mineralogy. Aragonite is the dominant phase. (2) About 10 000 years ago the ice had retreated beyond the basin margins and the large volume of water then covered areas once under ice. This spreading of lake waters increased the ablation surface, resulting in evaporative concentration of lake waters, and a reduction in lake levels. Brine concentration caused the precipitation of the aragonite unit D. 8
13C values indicate that biogenic processes continued to operate but were overshadowed by inorganic carbonate deposition. (3) Following the complete retreat of the Ross Sea ice, alpine glaciers then readvanced. Meltwaters therefrom flowed into the lake basin refilling the lake. Evaporated brines then rediffused up into the water column resulting in the present chemical stratification. Modification ofthe water column in the upper euphotic zone, mainly by photosynthetic algae, causes the precipitation of calcite which falls as a pelagic rain to the lake bed. Where the lake bed is within the euphotic zone, stromatolitic deposition occurs. In addition to the three depositional mechanisms, there may be diagenetic alteration of the carbonates in units B andD.