The purpose of this research was to study pyrolysis of glycerol to produce hydrogen using microwave. The use of microwave aimed to produce high temperatures, because pyrolysis require high temperature.The effect of kind of catalyst and microwave power were studied. The catalyst was activated carbon and Ni/HZSM-5.The catalyst of activated carbon was ready to use, whereas Ni/HZSM-5 catalyst was obtained by ion exchange from Na-ZSM-5 with NH 4 Cl and then HZSM-5 was impregnated with metal solution of Ni (NO 3 ) 2 .6 H 2 O. Experiments were conducted by mixing catalyst in the reactor together with glycerol solution of 10% (weight percent) as much as 100 ml. Reactor was made from pyrex and mounted on microwave equipped with a thermocouple. And then, reactor was heated on power of 400-700 Watt during thirty minutes. The reaction produced gases and liquid to be analyzed by chromatography gas.The conclusion stated that microwave could pyrolysis glycerol into hydrogen. By product of this reaction were methanol, allyl alcohol, acrolein and unidentified products. The difference of catalyst produced different product as well. The pyrolysis of glycerol using activated carbon produced conversion of 60 %, while using catalysts Ni/HZSM-5 obtained conversion of 87 %. The reaction produced hydrogen gases was relatively small for both of catalysts that is minimum of 0,59% and maximum of 0,88%.