Solid oxide fuel cell composite cathodes prepared by infiltration of copper manganese spinel into porous yttria stabilized zirconia

Zhang, Qi; Martin, Boris E.; Petric, Anthony

doi:10.1039/b808162j

Cited by 21 publications

(6 citation statements)

References 21 publications

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“…228 An attempt was also made to inltrate Cu-Mn spinel into a scaffold of YSZ for performance enhancement. 229 Comparative study of a variety of MIECs inltrated into a scaffold of YSZ on the cathode performance was performed with varied substitutions in the A-site 230,231 and B-site 232 in the LSF series. Modeling [233][234][235] and experiments 236 both showed that the scaffold properties have great inuence on performance of inltrated electrodes.…”

Section: Catalyst Inltrated Into Scaffolds Of Electrolytesmentioning

confidence: 99%

Enhancing SOFC cathode performance by surface modification through infiltration

Ding

Lai

et al. 2014

Energy Environ. Sci.

773

495

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Section: Catalyst Inltrated Into Scaffolds Of Electrolytesmentioning

confidence: 99%

Enhancing SOFC cathode performance by surface modification through infiltration

Ding

Lai

et al. 2014

Energy Environ. Sci.

773

495

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“…The spinel Cu 1.25 Mn 1.75 O 4 (CMO) has also been recently proposed 183 as a potential cathode for use with YSZ electrolytes. A cathode consisting of 50% CMO impregnated YSZ had a polarization resistance of 0.3 Ω cm -2 at 750 °C.…”

Section: New Cathode Materialsmentioning

confidence: 99%

New Chemical Systems for Solid Oxide Fuel Cells

2009

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In this review article, new systems being investigated for application in solid oxide fuel cells are discussed. For the electrode materials, materials with the perovskite or related structures continue to dominate the field, due to the need for high electronic conductivity. Research in this field is being directed toward compositions allowing high ionic conductivity in addition to their electronic contribution. In contrast, research on new electrolyte materials has shown a diverse range of structure-types, with an apparent tendency toward structures containing cations in lower coordination environments, particularly tetrahedral. In both the electrode and electrolyte area, materials allowing the incorporation of oxygen excess into interstitial sites have shown promising results, warranting further investigations of materials that will allow this type of defect chemistry.

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“…SOFCs 16,17 . Cu-Mn-O spinel has been proposed as a potential cathode 18 . The spinel oxides were used as the excellent potential candidate of the protective layer on ferric stainless steels to the cathode side 19,20 .…”

Section: Introductionmentioning

confidence: 99%

Effects of Precursor on Preparation and Properties of Nano-Crystalline Hopcalite Particles

Deraz¹,

Abd‐Elkader²

2014

Asian J. Chem.

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X-ray diffraction techniques used to determine the structural properties of hopcalite nanoparticles. A mixture of hopcalite and its constituents can be prepared by ceramic method at 800 °C for 5 h. The spinel structure of hopcalite (Cu-Mn-O) confirms by infrared measurements. The copper precursors affect the formation and different properties of hopcalite. Solid state reaction between CuO resulted from copper nitrate with Mn2O3 obtained from manganese carbonate brought about formation of spinel Cu1.5Mn1.5O4 compound with subsequent formation of both Mn2O3 and CuO. On the other hand, using of copper chloride as a source of CuO led to formation of both CuMn2O4 and Mn2O3. The results showed that the change of precursor led to different changes in the structural properties of hopcalite solid including the crystallite size, lattice constant, unit cell volume, X-ray density, the distance between the reacting ions, ionic radii and bond lengths on tetrahedral and octahedral sites involved in the spinel structure.

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Solid oxide fuel cell composite cathodes prepared by infiltration of copper manganese spinel into porous yttria stabilized zirconia

Cited by 21 publications

References 21 publications

Enhancing SOFC cathode performance by surface modification through infiltration

Enhancing SOFC cathode performance by surface modification through infiltration

New Chemical Systems for Solid Oxide Fuel Cells

Effects of Precursor on Preparation and Properties of Nano-Crystalline Hopcalite Particles

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