The nonlinear self-dual network equations that describe the propagations of electrical signals in nonlinear LC self-dual circuits are explored. We firstly analyse the modulation instability of the constant amplitude waves. Secondly, a novel generalized perturbation (
M
,
N
−
M
)-fold Darboux transform (DT) is proposed for the lattice system by means of the Taylor expansion and a parameter limit procedure. Thirdly, the obtained perturbation (1,
N
− 1)-fold DT is used to find its new higher-order rational solitons (RSs) in terms of determinants. These higher-order RSs differ from those known results in terms of hyperbolic functions. The abundant wave structures of the first-, second-, third- and fourth-order RSs are exhibited in detail. Their dynamical behaviours and stabilities are numerically simulated. These results may be useful for understanding the wave propagations of electrical signals.