Solubilities of benzoic acid in binary (benzyl alcohol+benzaldehyde) solvent mixtures

Wang, Hui; Wang, Qinbo; Xiong, Zhenhua; Chen, Chuxiong; Shen, Binwei

doi:10.1016/j.jct.2014.12.003

Cited by 34 publications

(44 citation statements)

References 19 publications

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“…The change of Gibbs free energy (Δ dis G) can be obtained by the equation 4 and equation 5 [28][29]:…”

Section: Resultsmentioning

confidence: 99%

“…Nevertheless, there is no report about the solubility data of CB[n] in different temperature, which is very important in the preparation, purification and application of CB [n]. In this study, the solubility of CB [5] in pure water and different concentration of hydrochloric acid aqueous solution were measured using UV−vis spectrophotometer method 28 at temperatures ranging from 283.15 to 323.15 K. The enthalpy, entropy, and Gibbs free energy of solution for CB [5] was calculated from the experiment data.…”

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

The Solubility of Cucurbit[5]uril in Pure Water and Hydrochloric Acid at Different Temperature and Some Relative Thermodynamic Functions

Han¹,

Li²

2015

Proceedings of the 5th International Conference on Information Engineering for Mechanics and Materials

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The solubility of cucurbit[5]uril in pure water and different concentration of hydrochloric acid aqueous solution(HCl:H 2 O = 10:110, 15:105, 20:100, 40:80) were investigated between 283.15 K and 323.15 K at atmospheric pressure by using the UV−vis spectrophotometer method. The solubility of CB[5] increased with the increasing of temperature, and a new phenomenon was found that the solubility of CB[5] increased with increasing acid concentration below 298 K and the solubility of CB[5] reduced with increasing acid concentration above 305 K. Thermodynamic functions (entropy and enthalpy of dissolution) for the CB[5] solutions were determined with the Van't Hoff equation, and the Gibbs free energy was also calculated.

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“…The change of Gibbs free energy (Δ dis G) can be obtained by the equation 4 and equation 5 [28][29]:…”

Section: Resultsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

The Solubility of Cucurbit[5]uril in Pure Water and Hydrochloric Acid at Different Temperature and Some Relative Thermodynamic Functions

Han¹,

Li²

2015

Proceedings of the 5th International Conference on Information Engineering for Mechanics and Materials

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“…Literarure reveals that few studies on the dissociation constants of benzoic acid and derivative of benzoic acids in alkanol-water mixtures by conductometric methods have been performed earlier. [4][5][6][7][8] But no report about the investigation on the conductometric studies of benzoic acid in 1-propanol mixture are available yet.…”

Section: Introductionmentioning

confidence: 99%

Conductimetric Properties of Benzoic Acid in Water and 1-Propanol Mixtures at the Temperatures from 298.15 to 313.15K

Kabir¹,

Nath²,

Hossain³

et al. 2018

Orient. J. Chem

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Molar conductance of benzoic acid in 1-propanol-water mixtures has been measured in the composition of 0, 5, 10, 15, 20, 30 and 40 wt % of 1-propanol at 5 K interval from 298.15 to 313.15 K. The limiting molar conductance Λ o and the thermodynamic dissociation constant constant pKa were estimated from the measured conductance data using Bray-Kraus and Fuoss-Kraus equations. An approximate linear dependence of pK a with the reciprocal of the dielectric constant of the media was observed and this trend may be due to the dominating effect of the coulombic forces of attractions between the opposite ions over the other types of attractions. The gradual decreases of Λ o with the increase of 1-propanol fraction in the binary mixtures of 1-propanol and water may be attributed to relative increase in the viscosities of 1-propanol-water mixtures. The Walden product and normalized Walden product (nwp) of the benzoic acid in the seven binary mixtures have been calculated and a qualitative proposal has been made regarding their variation with wt% of 1-propanol. The free energies of transfer ΔG°t r, also have been computed for the acid in the solvent mixtures. The change of pK a with the solvent composition has been discussed in terms of the free energy of transfer from water to the 1-propanol-water mixtures.

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“…Values of benzoic acid dissolution in binary mixture of solvent (benzyl alcohol and benzaldehyde) at 298.35-355.65 K and atmospheric pressure are given in [5]. It was determined that at constant composition of binary mixture the increase in temperature increases solubility.…”

Section: Introductionmentioning

confidence: 99%

Investigation of physical dissolution of benzoic acid polydisperse mixture

Symak¹,

Гумницький²,

Atamaniuk³

et al. 2017

ChChT

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Abstract.1 The dissolving process of benzoic acid polydisperse mixture in the gas-liquid flow has been examined. On the basis of criterial dependence and the theory of local isotropic turbulence the mass-transfer coefficient was determined experimentally and theoretically and their values were compared. Theoretical calculation of polydisperse mixture dissolution was performed during periodic dissolution under variable driving force. Theoretical and experimental results were compared.

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Solubilities of benzoic acid in binary (benzyl alcohol+benzaldehyde) solvent mixtures

Cited by 34 publications

References 19 publications

The Solubility of Cucurbit[5]uril in Pure Water and Hydrochloric Acid at Different Temperature and Some Relative Thermodynamic Functions

The Solubility of Cucurbit[5]uril in Pure Water and Hydrochloric Acid at Different Temperature and Some Relative Thermodynamic Functions

Conductimetric Properties of Benzoic Acid in Water and 1-Propanol Mixtures at the Temperatures from 298.15 to 313.15K

Investigation of physical dissolution of benzoic acid polydisperse mixture

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