Solubility in the ZnCl2-CO(NH2)2-HCl-H2O system at 25°C

Еркасов, Р. Ш.; Nesmeyanova, R. M.; Orazbaeva, R. S.; Bolysbekova, S. M.

doi:10.1134/s0036023613020046

Cited by 11 publications

(4 citation statements)

References 1 publication

Supporting

Mentioning

Contrasting

Order By: Relevance

“…In addition to NaCl, at least four equilibrium solid phases were involved in dissolution equilibrium: CaCl 2 ·6H 2 O, CaCl 2 ·4H 2 O, CaCl 2 ·ZnCl 2 · X H 2 O, and ZnCl 2 . The solubility of the ZnCl 2 –CO(NH 2 ) 2 –HCl–H 2 O system at 298.15 K has also been reported . Wang et al reported the phase diagram of the quaternary KCl–ZnCl 2 –HCl–H 2 O system at 298 K by the isothermal dissolution method and found the existence of a 5:4 new compound 5KCl·4ZnCl 2 ·3H 2 O .…”

Section: Introductionmentioning

confidence: 96%

Solid–Liquid Phase Equilibria in the Ternary Systems NaCl–ZnCl₂–H₂O and CaCl₂–ZnCl₂–H₂O at 323 K

Zhang

Zhou

2019

J. Chem. Eng. Data

View full text Add to dashboard Cite

This paper describes the results of the solid–liquid equilibria phase diagram in the two ternary systems sodium chloride–zinc chloride–water and calcium chloride–zinc chloride–water at 323 K using the method of isothermal dissolution equilibrium. Integrated with the determined equilibrated liquid phase and humid residue composition, the phase diagrams of the two systems were generated. At the same time, the invariant points, the univariant solubility curves, and the solid crystalline phase regions are displayed and discussed. The results of the experiment testify that the types of two ternary systems are classified as complex owing to the formation of a double salt. The phase diagram of the ternary system NaCl–ZnCl2–H2O at 323 K is constituted of two eutectic points, three univariant solubility curves, and three solid crystalline phase regions corresponding to NaCl, ZnCl2, and 2NaCl·ZnCl2. The phase diagram of the ternary system CaCl2–ZnCl2–H2O at 323 K includes two eutectic points, three univariant solubility curves, and three solid crystalline phase regions corresponding to CaCl2·2H2O, CaCl2·ZnCl2·2H2O, and ZnCl2. The experimental densities of the equilibrium solution were measured using a density bottle method. Based on the Laliberte model, the theoretical density of each saturated solution was calculated. The results show that the model gives worse prediction for two ternary systems with stronger interactions between components.

show abstract

Section: Introductionmentioning

confidence: 96%

Solid–Liquid Phase Equilibria in the Ternary Systems NaCl–ZnCl₂–H₂O and CaCl₂–ZnCl₂–H₂O at 323 K

Zhang

Zhou

2019

J. Chem. Eng. Data

View full text Add to dashboard Cite

show abstract

“…Because high density fluid is used as a petroleum drilling fluid, solubilities and densities of the ternary system CaCl 2 –ZnCl 2 –H 2 O have been carried out at 273.15 and 298.15 K and the system CaCl 2 +ZnCl 2 +H 2 O (NaCl saturated) was studied at T = 288.15 K . The solubilities of ZnCl 2 and CO(NH 2 ) 2 in HCl have been determined at T = 298.15 K . The phase equilibria of the ternary system ZnCl 2 –LiCl–H 2 O at 298 and 313 K have been conducted, and it was found that the double salt 2LiCl·ZnCl 2 ·2.5H 2 O was observed.…”

Section: Introductionmentioning

confidence: 99%

Phase Equilibria in the Quaternary Systems KCl–PbCl₂–ZnCl₂–H₂O and MgCl₂–PbCl₂–ZnCl₂–H₂O at 373 K

Zhang

Yang

et al. 2017

J. Chem. Eng. Data

View full text Add to dashboard Cite

In this work, the method of isothermal dissolution equilibrium was applied to investigating the phase equilibria of quaternary systems KCl−PbCl 2 −ZnCl 2 − H 2 O and MgCl 2 −PbCl 2 −ZnCl 2 −H 2 O at 373 K throughout the entire concentration range. Isothermal solubility and water content diagrams were constructed based on the measured solubility of components and the coexisting solid phase, respectively. The experimental results indicate that the phase diagram of the quaternary system KCl−PbCl 2 −ZnCl 2 −H 2 O at 373 K consists of three invariant points, seven univariant isothermal solubility curves, and five single solid-phase crystalline regions corresponding to KCl, PbCl 2 , KCl•2PbCl 2 , 2KCl•ZnCl 2 , and ZnCl 2 . It is shown that the phase diagram of the quaternary system MgCl 2 −PbCl 2 −ZnCl 2 −H 2 O at 373 K is made up of two invariant points, five univariant isothermal solubility curves, and four single solid-phase crystalline regions corresponding to MgCl 2 •6H 2 O, PbCl 2 , MgCl 2 •ZnCl 2 •5H 2 O, and ZnCl 2 .

show abstract

“…The solubility of ZnCl 2 and CO(NH 2 ) 2 mixtures in hydrochloric acid solution at T = 298.15 K has been carried out. 10 Lead solubility in aqueous chloride leach liquors containing HCl, CuCl 2 , and either NaCl or CaCl 2 were measured. 11 In the previous study, we have investigated the solubilities and densities of the ternary systems KCl−ZnCl 12,13 Although some relevant researches have been conducted, there has been no report about these two systems at any temperature.…”

Section: Introductionmentioning

confidence: 99%

“…Because of the application of high density fluids in petroleum production, solubilities and densities in CaCl 2 –ZnCl 2 –H 2 O system at 273.15 and 298.15 K and CaCl 2 + ZnCl 2 + H 2 O (NaCl saturated) at T = 288.15 K have been measured. The solubility of ZnCl 2 and CO(NH 2 ) 2 mixtures in hydrochloric acid solution at T = 298.15 K has been carried out . Lead solubility in aqueous chloride leach liquors containing HCl, CuCl 2 , and either NaCl or CaCl 2 were measured .…”

Section: Introductionmentioning

confidence: 99%

Measurement of Mineral Solubilities in the Quaternary Systems KCl–MgCl₂–ZnCl₂–H₂O and KCl–MgCl₂–PbCl₂–H₂O at 373 K

et al. 2017

View full text Add to dashboard Cite

In this work, the solubilities of the salt minerals in quaternary systems potassium chloride–magnesium chloride–zinc chloride–water and potassium chloride–magnesium chloride–lead chloride–water were measured at 373 K using an isothermal dissolution equilibrium method. Phase diagrams were constructed based on compositions of saturated liquid phase and existing equilibrium solid phase. By X-ray powder diffraction identification, a variety of solid forms were determined for the quaternary system KCl–MgCl2–ZnCl2–H2O at 373 K. Not only were three single salts KCl, ZnCl2, and MgCl2·6H2O determined but also three double salts KCl·MgCl2·6H2O(Car), 2KCl·ZnCl2, and MgCl2·ZnCl2·5H2O were detected. It also demonstrated that five precipitates KCl, MgCl2·6H2O, KCl·MgCl2·6H2O(Car), KCl·2PbCl2, and PbCl2 were formed in the quaternary system KCl–MgCl2–PbCl2–H2O at 373 K.

show abstract

Solubility in the ZnCl2-CO(NH2)2-HCl-H2O system at 25°C

Cited by 11 publications

References 1 publication

Solid–Liquid Phase Equilibria in the Ternary Systems NaCl–ZnCl₂–H₂O and CaCl₂–ZnCl₂–H₂O at 323 K

Solid–Liquid Phase Equilibria in the Ternary Systems NaCl–ZnCl₂–H₂O and CaCl₂–ZnCl₂–H₂O at 323 K

Phase Equilibria in the Quaternary Systems KCl–PbCl₂–ZnCl₂–H₂O and MgCl₂–PbCl₂–ZnCl₂–H₂O at 373 K

Measurement of Mineral Solubilities in the Quaternary Systems KCl–MgCl₂–ZnCl₂–H₂O and KCl–MgCl₂–PbCl₂–H₂O at 373 K

Contact Info

Product

Resources

About

Solubility in the ZnCl2-CO(NH2)2-HCl-H2O system at 25°C

Cited by 11 publications

References 1 publication

Solid–Liquid Phase Equilibria in the Ternary Systems NaCl–ZnCl2–H2O and CaCl2–ZnCl2–H2O at 323 K

Solid–Liquid Phase Equilibria in the Ternary Systems NaCl–ZnCl2–H2O and CaCl2–ZnCl2–H2O at 323 K

Phase Equilibria in the Quaternary Systems KCl–PbCl2–ZnCl2–H2O and MgCl2–PbCl2–ZnCl2–H2O at 373 K

Measurement of Mineral Solubilities in the Quaternary Systems KCl–MgCl2–ZnCl2–H2O and KCl–MgCl2–PbCl2–H2O at 373 K

Contact Info

Product

Resources

About

Solid–Liquid Phase Equilibria in the Ternary Systems NaCl–ZnCl₂–H₂O and CaCl₂–ZnCl₂–H₂O at 323 K

Solid–Liquid Phase Equilibria in the Ternary Systems NaCl–ZnCl₂–H₂O and CaCl₂–ZnCl₂–H₂O at 323 K

Phase Equilibria in the Quaternary Systems KCl–PbCl₂–ZnCl₂–H₂O and MgCl₂–PbCl₂–ZnCl₂–H₂O at 373 K

Measurement of Mineral Solubilities in the Quaternary Systems KCl–MgCl₂–ZnCl₂–H₂O and KCl–MgCl₂–PbCl₂–H₂O at 373 K