2021
DOI: 10.1021/acs.jced.1c00396
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Solubility Measurement, Preferential Solvation, and Solvent Effect of 3,5-Dinitrosalicylic Acid in Several Binary Aqueous Blends

Abstract: This research dealt with the equilibrium solubility, preferential solvation, and intra- and intermolecular interactions for 3,5-dinitrosalicylic acid dissolved in aqueous blends of N-methyl-2-pyrrolidinone (NMP)/ethanol/isopropanol/N,N-dimethylformamide (DMF) along with computational methodologies. All solubility experiments were performed using a shake-flask equilibration method under a pressure of 101.2 kPa from 278.15 to 323.15 K. For each aqueous blend, the minimum solubility value of 3,5-dinitrosalicylic … Show more

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Cited by 4 publications
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“…Currently, the measurement of solubility relies on numerous experiments, resulting in significant consumption of both time and organic solvents. Therefore, many thermodynamic models have been used to predict the solubility of solutes in different solvent systems including the NRTL, van’t Hoff, λh, and Jouyban–Acree models. Perturbed-chain statistical associating fluid theory (PC-SAFT) has also been successfully applied to describe the phase behavior and calculate the thermodynamic properties of the systems .…”
Section: Introductionmentioning
confidence: 99%
“…Currently, the measurement of solubility relies on numerous experiments, resulting in significant consumption of both time and organic solvents. Therefore, many thermodynamic models have been used to predict the solubility of solutes in different solvent systems including the NRTL, van’t Hoff, λh, and Jouyban–Acree models. Perturbed-chain statistical associating fluid theory (PC-SAFT) has also been successfully applied to describe the phase behavior and calculate the thermodynamic properties of the systems .…”
Section: Introductionmentioning
confidence: 99%