Solubility of he×achlorobenzene in organic nonelectrolyte solvents. Comparison of observed vs. predicted values based upon Mobile Order model

Fina, Karina M. De; Van, Tiffany T.; Acree, William E.

doi:10.1139/cjc-78-4-459

Cited by 3 publications

(3 citation statements)

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“…The solubilities of hexachlorobenzene ( T m = 501.7 K, H fus = 6099.4 cal/mol) in 30 solvents for which MOSCED parameters were available were used to regress parameters. The best-fit parameters result in a 26% AAE (see Figure ).…”

Section: Introductionmentioning

confidence: 99%

Revision of MOSCED Parameters and Extension to Solid Solubility Calculations

Lazzaroni¹,

Bush²,

Eckert³

et al. 2005

Ind. Eng. Chem. Res.

186

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New pure component parameters are presented for the MOSCED limiting activity coefficient model for 133 solvents with an absolute average deviation of 10.6% to experimental literature data. The MOSCED model has been applied to solid-liquid equilibria correlation and compared with the experimental data available in the literature. The correlation of solubility of 26 solids in organic solvents has an average absolute deviation of 25%. This compares favorably to the prediction of the modified UNIFAC model.

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Section: Introductionmentioning

confidence: 99%

Revision of MOSCED Parameters and Extension to Solid Solubility Calculations

Lazzaroni¹,

Bush²,

Eckert³

et al. 2005

Ind. Eng. Chem. Res.

186

View full text Add to dashboard Cite

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“…The simple one-parameter van der Waals one-fluid (vdW-1) mixing rules as represented by equations (7) and (8) were used. The kinematic viscosities for the mixtures mix ¼ ðV Þ mix were calculated by using equation (5). The kinematic viscosities of ideal mixtures id ¼ ðV Þ id were calculated by using the kinematic viscosities of pure components (2).…”

Section: Resultsmentioning

confidence: 99%

“…The organic solvent mixtures are important chemicals for the different industrial purposes such as solvent extraction of aromatic hydrocarbons from alkanes [1,2], crystallization and extraction of pure organic and mineral salts from aqueous mixtures [3,4] and solvent cleaning processes [5], therefore, measurements and modeling of thermodynamic and transport properties of the binary and ternary solvent mixtures have considerable current interest in chemical engineering research fields.…”

Section: Introductionmentioning

confidence: 99%

Experimental and theoretical studies of viscosities of ternary mixture [2-propanol+ethyl acetate+n-hexane] and its binary constituents at 298.15, 308.15 and 313.15 K

Modarress

Mohsen-Nia

2006

Physics and Chemistry of Liquids

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To cite this article: H. Modarress & M. Mohsen-Nia (2006) Experimental and theoretical studies of viscosities of ternary mixture [2-propanol+ethyl acetate+n-hexane] and its binary constituents at 298.15, 308.15 and 313.Experimental and theoretical studies of viscosities of ternary mixture [2-propanolQethyl acetateQn-hexane] and its binary constituents at 298.15, 308.15 and 313.15 K The viscosities of the ternary mixture [2-propanol þ ethyl acetate þ n-hexane] and its binary constituents; [2-propanol þ ethyl acetate], [2-propanol þ n-hexane] and [ethyl acetate þ n-hexane] were measured over the whole concentration range at three temperatures 298.15, 308.15 and 313.15 K. The M 4 cubic equation of state due to Mohsen-Nia et al. (M. MohsenNia, H. Modarress, G.A. Mansoori. Fluid Phase Equilibria, 206, 27 (2003)) was used along with the modified Eyring kinematic viscosity model to correlate the measured viscosity data and the interaction parameters for the binary mixtures are reported. The binary interaction parameters were successfully used for viscosity calculation of the ternary mixture.

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Excess molar volume measurements of ternary mixtures [2-propanol+ethyl acetate+n-hexane] and their binary constituents at 298.15, 308.15 and 313.15 K

Mohsen-Nia¹,

Modarress²

2005

Physics and Chemistry of Liquids

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Solubility of he×achlorobenzene in organic nonelectrolyte solvents. Comparison of observed vs. predicted values based upon Mobile Order model

Cited by 3 publications

References 0 publications

Revision of MOSCED Parameters and Extension to Solid Solubility Calculations

Revision of MOSCED Parameters and Extension to Solid Solubility Calculations

Experimental and theoretical studies of viscosities of ternary mixture [2-propanol+ethyl acetate+n-hexane] and its binary constituents at 298.15, 308.15 and 313.15 K

Excess molar volume measurements of ternary mixtures [2-propanol+ethyl acetate+n-hexane] and their binary constituents at 298.15, 308.15 and 313.15 K

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