Solubility of non polar gases in formaldehyde diethyl acetal between-10 and 30�C, and 1 Atm partial pressure of gas

Lizano, L. P.; López, M.C.; Royo, F.M.; Urieta, José S.

doi:10.1007/bf00647390

Cited by 6 publications

(3 citation statements)

References 12 publications

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“…Measurements were made using a volumetric method with an apparatus 9 based on that of Ben-Naim and Baer made of glass with Teflon valves. We have used this apparatus widely to measure solubilities of slightly soluble gases (He, Ne, Ar, Kr, Xe, N 2 , H 2 , D 2 , O 2 , CH 4 , C 2 H 6 , C 2 H 4 , CF 4 , SF 6 , and CO 2 ) in an extensive series of single organic compounds − and liquid mixtures…”

Section: Methodsmentioning

confidence: 99%

“…Measurements were made using a volumetric method with an apparatus 9 based on that of Ben-Naim and Baer 14 made of glass with Teflon valves. We have used this apparatus widely to measure solubilities of slightly soluble gases (He, Ne, Ar, Kr, Xe, N 2 , H 2 , D 2 , O 2 , CH 4 , C 2 H 6 , C 2 H 4 , CF 4 , SF 6 , and CO 2 ) in an extensive series of single organic compounds [15][16][17][18] and liquid mixtures. 19 As shown in Figure 1, the experimental equipment consists of a solution vessel, a buret system, and a mercury manometer to measure and control the pressure with a cathetometer, WILD KM 338 ((2.7 × 10 -3 kPa).…”

Section: Methodsmentioning

confidence: 99%

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Experimental and Predicted Solubilities of HFC134a (1,1,1,2-Tetrafluoroethane) in Polyethers

López

Mainar

Garcı́a

et al. 2004

Ind. Eng. Chem. Res.

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Experimental solubilities were determined for 1,1,1,2-tetrafluoroethane (HFC134a) in triethylene glycol dimethyl ether and in tetraethylene glycol dimethyl ether at 101.33 kPa refrigerant partial pressure in the low-temperature range (258.15-298.15 K). The experimental device was adapted from an apparatus commonly used to measure slightly soluble gases. Because HFC134a was highly soluble in the two polyglycols, the mole fraction of the refrigerant was calculated by the φ-γ method and the symmetrical criteria for the components. The solubilities of the refrigerant in the two solvents were very similar. The thermodynamic quantities related to the solution process were also obtained from the solubility data. The isobaric solubilities predicted by the original and Dortmund UNIFAC versions were compared with the experimental values to test the interaction parameters of Kleiber (Fluid

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Section: Methodsmentioning

confidence: 99%

Section: Methodsmentioning

confidence: 99%

Experimental and Predicted Solubilities of HFC134a (1,1,1,2-Tetrafluoroethane) in Polyethers

López

Mainar

Garcı́a

et al. 2004

Ind. Eng. Chem. Res.

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“…A dataset containing mole fraction solubility values (χ) for 280 liquid solvents at 298.15 K and 1 atm was collected (Table S1, Supporting Information) from IUPAC reports, − scientific literature, − and patents. , The mole fraction solubility for a binary (gas–liquid) system is defined as where n (g) is the amount of the dissolved gas and n (l) is the amount of solvent.…”

Section: Materials and Methodsmentioning

confidence: 99%

Chemoinformatics-Driven Design of New Physical Solvents for Selective CO₂ Absorption

Orlov

Demenko

Bignaud

et al. 2021

Environ. Sci. Technol.

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The removal of CO 2 from gases is an important industrial process in the transition to a lowcarbon economy. The use of selective physical (co-)solvents is especially perspective in cases when the amount of CO 2 is large as it enables one to lower the energy requirements for solvent regeneration. However, only a few physical solvents have found industrial application and the design of new ones can pave the way to more efficient gas treatment techniques. Experimental screening of gas solubility is a labor-intensive process, and solubility modeling is a viable strategy to reduce the number of solvents subject to experimental measurements. In this paper, a chemoinformatics-based modeling workflow was applied to build a predictive model for the solubility of CO 2 and four other industrially important gases (CO, CH 4 , H 2 , N 2 ). A dataset containing solubilities of gases in 280 solvents was collected from literature sources and supplemented with the new data for six solvents measured in the present study. A modeling workflow based on the usage of several state-of-the-art machine learning algorithms was applied to establish quantitative structure-solubility relationships. The best models were used to perform virtual screening of the industrially produced chemicals. It enabled the identification of compounds with high predicted CO 2 solubility and selectivity towards the other gases. The prediction for one of the compounds − 4-Methylmorpholine was confirmed experimentally. SYNOPSIS STATEMENTDeveloping better solvents for selective CO 2 capture is crucial for reaching net-zero emissions targets.4

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Solubility of nonpolar gases in tetrahydrofuran at 0 to 30�C and 101.33 kPa partial pressure of gas

et al. 1993

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Solubility of non polar gases in formaldehyde diethyl acetal between-10 and 30�C, and 1 Atm partial pressure of gas

Cited by 6 publications

References 12 publications

Experimental and Predicted Solubilities of HFC134a (1,1,1,2-Tetrafluoroethane) in Polyethers

Experimental and Predicted Solubilities of HFC134a (1,1,1,2-Tetrafluoroethane) in Polyethers

Chemoinformatics-Driven Design of New Physical Solvents for Selective CO₂ Absorption

Solubility of nonpolar gases in tetrahydrofuran at 0 to 30�C and 101.33 kPa partial pressure of gas

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Solubility of non polar gases in formaldehyde diethyl acetal between-10 and 30�C, and 1 Atm partial pressure of gas

Cited by 6 publications

References 12 publications

Experimental and Predicted Solubilities of HFC134a (1,1,1,2-Tetrafluoroethane) in Polyethers

Experimental and Predicted Solubilities of HFC134a (1,1,1,2-Tetrafluoroethane) in Polyethers

Chemoinformatics-Driven Design of New Physical Solvents for Selective CO2 Absorption

Solubility of nonpolar gases in tetrahydrofuran at 0 to 30�C and 101.33 kPa partial pressure of gas

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Chemoinformatics-Driven Design of New Physical Solvents for Selective CO₂ Absorption