2012
DOI: 10.1016/j.electacta.2012.01.104
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Solution synthesis of nanometric layered cobalt oxides for electrochemical applications

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Cited by 24 publications
(14 citation statements)
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“…To further elucidate the cause of the rise in the capacitance, the Trasatti procedure was performed. 39,40 This allows us to discriminate charge storage due to the easily accessible surface (outer, q o ) and not easily accessible surface (inner, q i ). The specific charge (q * ) is the total charge exchanged between electrode and electrolyte, including both inner and outer charge storage, as shown in eqn (3).…”
Section: Electrochemical Characterizationmentioning
confidence: 99%
“…To further elucidate the cause of the rise in the capacitance, the Trasatti procedure was performed. 39,40 This allows us to discriminate charge storage due to the easily accessible surface (outer, q o ) and not easily accessible surface (inner, q i ). The specific charge (q * ) is the total charge exchanged between electrode and electrolyte, including both inner and outer charge storage, as shown in eqn (3).…”
Section: Electrochemical Characterizationmentioning
confidence: 99%
“…[9][10][11] Several metal oxides/(oxy)hydroxides such as RuO 2 , MnO 2 , Co(OH) 2 , Ni(OH) 2 , Co 3 O 4 , HCoO 2 , and NiCoO 2 have been widely investigated and show promising features. [12][13][14][15][16][17][18][19][20][21] However, for all of them, nano-structuration to optimize the electrode-electrolyte interface and a conductive scaffold to improve their electronic conductivity are crucial for maximizing their performances. [22][23][24] Among all these electrode materials, non-stoichiometric layered cobalt oxyhydroxide (HCoO 2 ) offers a two dimensional structure suitable for fast ionic diffusion as well as a good intrinsic electronic conductivity due the high oxidation state of cobalt, which favors electron transportation.…”
Section: Introductionmentioning
confidence: 99%
“…To further understand the electrochemical energy storage behavior of sample PS and sample DPS-1 in the 1 M LiClO 4 , scan rate dependent Trasatti analysis was carried out at different scan rates. 26,27 This allows us to discriminate charge storage due to easily accessible surfaces (outer, q o ) and the inner surfaces (inner, q i ). The specific charge (q*) is the total charge exchanged between the electrode and the electrolyte, including both inner and outer charge storage, as shown in Eq.…”
Section: A Structural Characterizationmentioning
confidence: 99%